Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin

Autores
D'ippolito, Silvana Andrea; Ballarini, Adriana Daniela; Rosas, Santiago Miguel; Pirault Roy, Laurence; Especel, Catherine; Epron, Florence; Pieck, Carlos Luis
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The influence of Ir content on sulphur tolerance for the selective ring opening of decalin was investigated. Ir/SiO2-Al2O3 catalysts (70 wt% and 80 wt% SiO2) were used. In the absence of sulphur, slight differences were observed on the yields according to the metallic content regardless of the support used. Although the results of cyclopentane hydrogenolysis showed that the metallic function acquires importance as the metal content increases, for these metal percentages the acid function limits the rate of decalin opening reaction. Products distribution are strongly modified using decalin with S content compared to pure decalin. The formation of dehydrogenated products is virtually null due to S adsorbed on the metal sites. The support has low influence on the thiotolerance. The results, related to the amount of S per Ir surface atom, showed that for a moderate S content (S/Irsurf ∼ 0.30), 1.5 Ir/Sy appears to be less poisoned than 1Ir/Sy and 2Ir/Sy.
Fil: D'ippolito, Silvana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ballarini, Adriana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rosas, Santiago Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pirault Roy, Laurence. Université de Poitiers; Francia
Fil: Especel, Catherine. Université de Poitiers; Francia
Fil: Epron, Florence. Université de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
DECALIN
IR/SIO2-AL2O3
SELECTIVE RING OPENING
THIOTOLERANCE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/146246
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/146246
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalinD'ippolito, Silvana AndreaBallarini, Adriana DanielaRosas, Santiago MiguelPirault Roy, LaurenceEspecel, CatherineEpron, FlorencePieck, Carlos LuisDECALINIR/SIO2-AL2O3SELECTIVE RING OPENINGTHIOTOLERANCEhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of Ir content on sulphur tolerance for the selective ring opening of decalin was investigated. Ir/SiO2-Al2O3 catalysts (70 wt% and 80 wt% SiO2) were used. In the absence of sulphur, slight differences were observed on the yields according to the metallic content regardless of the support used. Although the results of cyclopentane hydrogenolysis showed that the metallic function acquires importance as the metal content increases, for these metal percentages the acid function limits the rate of decalin opening reaction. Products distribution are strongly modified using decalin with S content compared to pure decalin. The formation of dehydrogenated products is virtually null due to S adsorbed on the metal sites. The support has low influence on the thiotolerance. The results, related to the amount of S per Ir surface atom, showed that for a moderate S content (S/Irsurf ∼ 0.30), 1.5 Ir/Sy appears to be less poisoned than 1Ir/Sy and 2Ir/Sy.Fil: D'ippolito, Silvana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Ballarini, Adriana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Rosas, Santiago Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Pirault Roy, Laurence. Université de Poitiers; FranciaFil: Especel, Catherine. Université de Poitiers; FranciaFil: Epron, Florence. Université de Poitiers; FranciaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaJohn Wiley & Sons Inc2021-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/146246D'ippolito, Silvana Andrea; Ballarini, Adriana Daniela; Rosas, Santiago Miguel; Pirault Roy, Laurence; Especel, Catherine; et al.; Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin; John Wiley & Sons Inc; The Canadian Journal Of Chemical Engineering; 99; 5; 5-2021; 1146-11570008-4034CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/cjce.23930info:eu-repo/semantics/altIdentifier/doi/10.1002/cjce.23930info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:55:12Zoai:ri.conicet.gov.ar:11336/146246instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:55:12.491CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin
title Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin
spellingShingle Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin
D'ippolito, Silvana Andrea
DECALIN
IR/SIO2-AL2O3
SELECTIVE RING OPENING
THIOTOLERANCE
title_short Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin
title_full Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin
title_fullStr Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin
title_full_unstemmed Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin
title_sort Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin
dc.creator.none.fl_str_mv D'ippolito, Silvana Andrea
Ballarini, Adriana Daniela
Rosas, Santiago Miguel
Pirault Roy, Laurence
Especel, Catherine
Epron, Florence
Pieck, Carlos Luis
author D'ippolito, Silvana Andrea
author_facet D'ippolito, Silvana Andrea
Ballarini, Adriana Daniela
Rosas, Santiago Miguel
Pirault Roy, Laurence
Especel, Catherine
Epron, Florence
Pieck, Carlos Luis
author_role author
author2 Ballarini, Adriana Daniela
Rosas, Santiago Miguel
Pirault Roy, Laurence
Especel, Catherine
Epron, Florence
Pieck, Carlos Luis
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv DECALIN
IR/SIO2-AL2O3
SELECTIVE RING OPENING
THIOTOLERANCE
topic DECALIN
IR/SIO2-AL2O3
SELECTIVE RING OPENING
THIOTOLERANCE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The influence of Ir content on sulphur tolerance for the selective ring opening of decalin was investigated. Ir/SiO2-Al2O3 catalysts (70 wt% and 80 wt% SiO2) were used. In the absence of sulphur, slight differences were observed on the yields according to the metallic content regardless of the support used. Although the results of cyclopentane hydrogenolysis showed that the metallic function acquires importance as the metal content increases, for these metal percentages the acid function limits the rate of decalin opening reaction. Products distribution are strongly modified using decalin with S content compared to pure decalin. The formation of dehydrogenated products is virtually null due to S adsorbed on the metal sites. The support has low influence on the thiotolerance. The results, related to the amount of S per Ir surface atom, showed that for a moderate S content (S/Irsurf ∼ 0.30), 1.5 Ir/Sy appears to be less poisoned than 1Ir/Sy and 2Ir/Sy.
Fil: D'ippolito, Silvana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ballarini, Adriana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rosas, Santiago Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pirault Roy, Laurence. Université de Poitiers; Francia
Fil: Especel, Catherine. Université de Poitiers; Francia
Fil: Epron, Florence. Université de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The influence of Ir content on sulphur tolerance for the selective ring opening of decalin was investigated. Ir/SiO2-Al2O3 catalysts (70 wt% and 80 wt% SiO2) were used. In the absence of sulphur, slight differences were observed on the yields according to the metallic content regardless of the support used. Although the results of cyclopentane hydrogenolysis showed that the metallic function acquires importance as the metal content increases, for these metal percentages the acid function limits the rate of decalin opening reaction. Products distribution are strongly modified using decalin with S content compared to pure decalin. The formation of dehydrogenated products is virtually null due to S adsorbed on the metal sites. The support has low influence on the thiotolerance. The results, related to the amount of S per Ir surface atom, showed that for a moderate S content (S/Irsurf ∼ 0.30), 1.5 Ir/Sy appears to be less poisoned than 1Ir/Sy and 2Ir/Sy.
publishDate 2021
dc.date.none.fl_str_mv 2021-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/146246
D'ippolito, Silvana Andrea; Ballarini, Adriana Daniela; Rosas, Santiago Miguel; Pirault Roy, Laurence; Especel, Catherine; et al.; Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin; John Wiley & Sons Inc; The Canadian Journal Of Chemical Engineering; 99; 5; 5-2021; 1146-1157
0008-4034
CONICET Digital
CONICET
url http://hdl.handle.net/11336/146246
identifier_str_mv D'ippolito, Silvana Andrea; Ballarini, Adriana Daniela; Rosas, Santiago Miguel; Pirault Roy, Laurence; Especel, Catherine; et al.; Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin; John Wiley & Sons Inc; The Canadian Journal Of Chemical Engineering; 99; 5; 5-2021; 1146-1157
0008-4034
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/cjce.23930
info:eu-repo/semantics/altIdentifier/doi/10.1002/cjce.23930
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083085891796992
score 13.22299

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