Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin
- Autores
- D'ippolito, Silvana Andrea; Ballarini, Adriana Daniela; Rosas, Santiago Miguel; Pirault Roy, Laurence; Especel, Catherine; Epron, Florence; Pieck, Carlos Luis
- Año de publicación
- 2021
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The influence of Ir content on sulphur tolerance for the selective ring opening of decalin was investigated. Ir/SiO2-Al2O3 catalysts (70 wt% and 80 wt% SiO2) were used. In the absence of sulphur, slight differences were observed on the yields according to the metallic content regardless of the support used. Although the results of cyclopentane hydrogenolysis showed that the metallic function acquires importance as the metal content increases, for these metal percentages the acid function limits the rate of decalin opening reaction. Products distribution are strongly modified using decalin with S content compared to pure decalin. The formation of dehydrogenated products is virtually null due to S adsorbed on the metal sites. The support has low influence on the thiotolerance. The results, related to the amount of S per Ir surface atom, showed that for a moderate S content (S/Irsurf ∼ 0.30), 1.5 Ir/Sy appears to be less poisoned than 1Ir/Sy and 2Ir/Sy.
Fil: D'ippolito, Silvana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Ballarini, Adriana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Rosas, Santiago Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Pirault Roy, Laurence. Université de Poitiers; Francia
Fil: Especel, Catherine. Université de Poitiers; Francia
Fil: Epron, Florence. Université de Poitiers; Francia
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina - Materia
-
DECALIN
IR/SIO2-AL2O3
SELECTIVE RING OPENING
THIOTOLERANCE - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/146246
Ver los metadatos del registro completo
id |
CONICETDig_07ebd045721546542cf414d71d79138d |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/146246 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalinD'ippolito, Silvana AndreaBallarini, Adriana DanielaRosas, Santiago MiguelPirault Roy, LaurenceEspecel, CatherineEpron, FlorencePieck, Carlos LuisDECALINIR/SIO2-AL2O3SELECTIVE RING OPENINGTHIOTOLERANCEhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of Ir content on sulphur tolerance for the selective ring opening of decalin was investigated. Ir/SiO2-Al2O3 catalysts (70 wt% and 80 wt% SiO2) were used. In the absence of sulphur, slight differences were observed on the yields according to the metallic content regardless of the support used. Although the results of cyclopentane hydrogenolysis showed that the metallic function acquires importance as the metal content increases, for these metal percentages the acid function limits the rate of decalin opening reaction. Products distribution are strongly modified using decalin with S content compared to pure decalin. The formation of dehydrogenated products is virtually null due to S adsorbed on the metal sites. The support has low influence on the thiotolerance. The results, related to the amount of S per Ir surface atom, showed that for a moderate S content (S/Irsurf ∼ 0.30), 1.5 Ir/Sy appears to be less poisoned than 1Ir/Sy and 2Ir/Sy.Fil: D'ippolito, Silvana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Ballarini, Adriana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Rosas, Santiago Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Pirault Roy, Laurence. Université de Poitiers; FranciaFil: Especel, Catherine. Université de Poitiers; FranciaFil: Epron, Florence. Université de Poitiers; FranciaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaJohn Wiley & Sons Inc2021-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/146246D'ippolito, Silvana Andrea; Ballarini, Adriana Daniela; Rosas, Santiago Miguel; Pirault Roy, Laurence; Especel, Catherine; et al.; Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin; John Wiley & Sons Inc; The Canadian Journal Of Chemical Engineering; 99; 5; 5-2021; 1146-11570008-4034CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/cjce.23930info:eu-repo/semantics/altIdentifier/doi/10.1002/cjce.23930info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:59:30Zoai:ri.conicet.gov.ar:11336/146246instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:59:31.269CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin |
title |
Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin |
spellingShingle |
Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin D'ippolito, Silvana Andrea DECALIN IR/SIO2-AL2O3 SELECTIVE RING OPENING THIOTOLERANCE |
title_short |
Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin |
title_full |
Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin |
title_fullStr |
Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin |
title_full_unstemmed |
Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin |
title_sort |
Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin |
dc.creator.none.fl_str_mv |
D'ippolito, Silvana Andrea Ballarini, Adriana Daniela Rosas, Santiago Miguel Pirault Roy, Laurence Especel, Catherine Epron, Florence Pieck, Carlos Luis |
author |
D'ippolito, Silvana Andrea |
author_facet |
D'ippolito, Silvana Andrea Ballarini, Adriana Daniela Rosas, Santiago Miguel Pirault Roy, Laurence Especel, Catherine Epron, Florence Pieck, Carlos Luis |
author_role |
author |
author2 |
Ballarini, Adriana Daniela Rosas, Santiago Miguel Pirault Roy, Laurence Especel, Catherine Epron, Florence Pieck, Carlos Luis |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
DECALIN IR/SIO2-AL2O3 SELECTIVE RING OPENING THIOTOLERANCE |
topic |
DECALIN IR/SIO2-AL2O3 SELECTIVE RING OPENING THIOTOLERANCE |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The influence of Ir content on sulphur tolerance for the selective ring opening of decalin was investigated. Ir/SiO2-Al2O3 catalysts (70 wt% and 80 wt% SiO2) were used. In the absence of sulphur, slight differences were observed on the yields according to the metallic content regardless of the support used. Although the results of cyclopentane hydrogenolysis showed that the metallic function acquires importance as the metal content increases, for these metal percentages the acid function limits the rate of decalin opening reaction. Products distribution are strongly modified using decalin with S content compared to pure decalin. The formation of dehydrogenated products is virtually null due to S adsorbed on the metal sites. The support has low influence on the thiotolerance. The results, related to the amount of S per Ir surface atom, showed that for a moderate S content (S/Irsurf ∼ 0.30), 1.5 Ir/Sy appears to be less poisoned than 1Ir/Sy and 2Ir/Sy. Fil: D'ippolito, Silvana Andrea. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Ballarini, Adriana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Rosas, Santiago Miguel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Pirault Roy, Laurence. Université de Poitiers; Francia Fil: Especel, Catherine. Université de Poitiers; Francia Fil: Epron, Florence. Université de Poitiers; Francia Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina |
description |
The influence of Ir content on sulphur tolerance for the selective ring opening of decalin was investigated. Ir/SiO2-Al2O3 catalysts (70 wt% and 80 wt% SiO2) were used. In the absence of sulphur, slight differences were observed on the yields according to the metallic content regardless of the support used. Although the results of cyclopentane hydrogenolysis showed that the metallic function acquires importance as the metal content increases, for these metal percentages the acid function limits the rate of decalin opening reaction. Products distribution are strongly modified using decalin with S content compared to pure decalin. The formation of dehydrogenated products is virtually null due to S adsorbed on the metal sites. The support has low influence on the thiotolerance. The results, related to the amount of S per Ir surface atom, showed that for a moderate S content (S/Irsurf ∼ 0.30), 1.5 Ir/Sy appears to be less poisoned than 1Ir/Sy and 2Ir/Sy. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/146246 D'ippolito, Silvana Andrea; Ballarini, Adriana Daniela; Rosas, Santiago Miguel; Pirault Roy, Laurence; Especel, Catherine; et al.; Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin; John Wiley & Sons Inc; The Canadian Journal Of Chemical Engineering; 99; 5; 5-2021; 1146-1157 0008-4034 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/146246 |
identifier_str_mv |
D'ippolito, Silvana Andrea; Ballarini, Adriana Daniela; Rosas, Santiago Miguel; Pirault Roy, Laurence; Especel, Catherine; et al.; Influence of the Ir content and the support on the thiotolerance of the Ir/SiO2-Al2O3 catalysts for selective ring opening of decalin; John Wiley & Sons Inc; The Canadian Journal Of Chemical Engineering; 99; 5; 5-2021; 1146-1157 0008-4034 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/10.1002/cjce.23930 info:eu-repo/semantics/altIdentifier/doi/10.1002/cjce.23930 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
John Wiley & Sons Inc |
publisher.none.fl_str_mv |
John Wiley & Sons Inc |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613765591465984 |
score |
13.070432 |