Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability

Autores
Celli, G.; Cairns, W.R.L.; Scarchilli, C.; Cuevas, Carlos A.; Saiz López, Alfonso; Savarino, J.; Stenni, B.; Frezzotti, M.; Becagli, S.; Delmonte, B.; Angot, H.; Fernandez, Rafael Pedro; Spolaor, Andrea
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
During the East Antarctic International Ice Sheet Traverse (Eaiist, december 2019), in an unexplored part of the East Antarctic Plateau, snow samples were collected to expand our knowledge of the latitudinal variability of iodine, bromine and sodium as well as their relation in connection with emission processes and photochemical activation in this unexplored area. A total of 32 surface (0–5 cm) and 32 bulk (average of 1 m depth) samples were taken and analysed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Our results show that there is no relevant latitudinal trend for bromine and sodium. For bromine they also show that it has no sig­nificant post-depositional mechanisms while its inland surface snow concentration is influenced by spring coastal bromine explosions. Iodine concentrations are several orders of magnitude lower than bromine and sodium and they show a decreasing trend in the surface samples concentration moving southward. This suggests that other processes affect its accumulation in surface snow, probably related to the radial reduction in the ozone layer moving towards central Antarctica. Even though all iodine, bromine and sodium present similar long-range transport from the dominant coastal Antarctic sources, the annual seasonal cycle of the ozone hole over Antarctica increases the amount of UV radiation (in the 280–320 nm range) reaching the surface, thereby affecting the surface snow photoactivation of iodine. A comparison between the bulk and surface samples supports the conclusion that iodine undergoes spring and summer snow recycling that increases its atmospheric lifetime, while it tends to accumulate during the winter months when photochemistry ceases.
Fil: Celli, G.. Ca’Foscari University of Venice; Italia
Fil: Cairns, W.R.L.. Ca’Foscari University of Venice; Italia. Consiglio Nazionale Delle Ricerche. Istituto Di Scienze Polari.; Italia
Fil: Scarchilli, C.. Università Roma Tre Iii. Dipartimento Di Scienze.; Italia
Fil: Cuevas, Carlos A.. Consejo Superior de Investigaciones Cientificas. Instituto de Quimica Fisica "rocasolano". Departamento de Quimica Atmosferica y Clima; España
Fil: Saiz López, Alfonso. Consejo Superior de Investigaciones Cientificas. Instituto de Quimica Fisica "rocasolano". Departamento de Quimica Atmosferica y Clima; España
Fil: Savarino, J.. Universite Grenoble Alpes.; Francia
Fil: Stenni, B.. Ca’Foscari University of Venice; Italia
Fil: Frezzotti, M.. Agenzia nazionale per le nuove tecnologie, l'energia e lo sviluppo económico sostenibile; Italia
Fil: Becagli, S.. Consiglio Nazionale Delle Ricerche. Istituto Di Scienze Polari.; Italia. Università degli Studi di Firenze; Italia
Fil: Delmonte, B.. Department Of Earth And Environmental Sciences (disat) ; Universita Degli Studi Di Milano;
Fil: Angot, H.. Universite Grenoble Alpes.; Francia
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina
Fil: Spolaor, Andrea. Consiglio Nazionale Delle Ricerche. Istituto Di Scienze Polari.; Italia
Materia
Ice-core records
Bromine Iodine
EAIIST traverse
Antarctica
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/245079
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/245079
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variabilityCelli, G.Cairns, W.R.L.Scarchilli, C.Cuevas, Carlos A.Saiz López, AlfonsoSavarino, J.Stenni, B.Frezzotti, M.Becagli, S.Delmonte, B.Angot, H.Fernandez, Rafael PedroSpolaor, AndreaIce-core recordsBromine IodineEAIIST traverseAntarcticahttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1During the East Antarctic International Ice Sheet Traverse (Eaiist, december 2019), in an unexplored part of the East Antarctic Plateau, snow samples were collected to expand our knowledge of the latitudinal variability of iodine, bromine and sodium as well as their relation in connection with emission processes and photochemical activation in this unexplored area. A total of 32 surface (0–5 cm) and 32 bulk (average of 1 m depth) samples were taken and analysed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Our results show that there is no relevant latitudinal trend for bromine and sodium. For bromine they also show that it has no sig­nificant post-depositional mechanisms while its inland surface snow concentration is influenced by spring coastal bromine explosions. Iodine concentrations are several orders of magnitude lower than bromine and sodium and they show a decreasing trend in the surface samples concentration moving southward. This suggests that other processes affect its accumulation in surface snow, probably related to the radial reduction in the ozone layer moving towards central Antarctica. Even though all iodine, bromine and sodium present similar long-range transport from the dominant coastal Antarctic sources, the annual seasonal cycle of the ozone hole over Antarctica increases the amount of UV radiation (in the 280–320 nm range) reaching the surface, thereby affecting the surface snow photoactivation of iodine. A comparison between the bulk and surface samples supports the conclusion that iodine undergoes spring and summer snow recycling that increases its atmospheric lifetime, while it tends to accumulate during the winter months when photochemistry ceases.Fil: Celli, G.. Ca’Foscari University of Venice; ItaliaFil: Cairns, W.R.L.. Ca’Foscari University of Venice; Italia. Consiglio Nazionale Delle Ricerche. Istituto Di Scienze Polari.; ItaliaFil: Scarchilli, C.. Università Roma Tre Iii. Dipartimento Di Scienze.; ItaliaFil: Cuevas, Carlos A.. Consejo Superior de Investigaciones Cientificas. Instituto de Quimica Fisica "rocasolano". Departamento de Quimica Atmosferica y Clima; EspañaFil: Saiz López, Alfonso. Consejo Superior de Investigaciones Cientificas. Instituto de Quimica Fisica "rocasolano". Departamento de Quimica Atmosferica y Clima; EspañaFil: Savarino, J.. Universite Grenoble Alpes.; FranciaFil: Stenni, B.. Ca’Foscari University of Venice; ItaliaFil: Frezzotti, M.. Agenzia nazionale per le nuove tecnologie, l'energia e lo sviluppo económico sostenibile; ItaliaFil: Becagli, S.. Consiglio Nazionale Delle Ricerche. Istituto Di Scienze Polari.; Italia. Università degli Studi di Firenze; ItaliaFil: Delmonte, B.. Department Of Earth And Environmental Sciences (disat) ; Universita Degli Studi Di Milano;Fil: Angot, H.. Universite Grenoble Alpes.; FranciaFil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; ArgentinaFil: Spolaor, Andrea. Consiglio Nazionale Delle Ricerche. Istituto Di Scienze Polari.; ItaliaAcademic Press Inc Elsevier Science2023-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/245079Celli, G.; Cairns, W.R.L.; Scarchilli, C.; Cuevas, Carlos A.; Saiz López, Alfonso; et al.; Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability; Academic Press Inc Elsevier Science; Environmental Research; 239; 10-2023; 1-100013-93511096-0953CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0013935123021485info:eu-repo/semantics/altIdentifier/doi/10.1016/j.envres.2023.117344info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:03:17Zoai:ri.conicet.gov.ar:11336/245079instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:03:18.0CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability
title Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability
spellingShingle Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability
Celli, G.
Ice-core records
Bromine Iodine
EAIIST traverse
Antarctica
title_short Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability
title_full Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability
title_fullStr Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability
title_full_unstemmed Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability
title_sort Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability
dc.creator.none.fl_str_mv Celli, G.
Cairns, W.R.L.
Scarchilli, C.
Cuevas, Carlos A.
Saiz López, Alfonso
Savarino, J.
Stenni, B.
Frezzotti, M.
Becagli, S.
Delmonte, B.
Angot, H.
Fernandez, Rafael Pedro
Spolaor, Andrea
author Celli, G.
author_facet Celli, G.
Cairns, W.R.L.
Scarchilli, C.
Cuevas, Carlos A.
Saiz López, Alfonso
Savarino, J.
Stenni, B.
Frezzotti, M.
Becagli, S.
Delmonte, B.
Angot, H.
Fernandez, Rafael Pedro
Spolaor, Andrea
author_role author
author2 Cairns, W.R.L.
Scarchilli, C.
Cuevas, Carlos A.
Saiz López, Alfonso
Savarino, J.
Stenni, B.
Frezzotti, M.
Becagli, S.
Delmonte, B.
Angot, H.
Fernandez, Rafael Pedro
Spolaor, Andrea
author2_role author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Ice-core records
Bromine Iodine
EAIIST traverse
Antarctica
topic Ice-core records
Bromine Iodine
EAIIST traverse
Antarctica
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv During the East Antarctic International Ice Sheet Traverse (Eaiist, december 2019), in an unexplored part of the East Antarctic Plateau, snow samples were collected to expand our knowledge of the latitudinal variability of iodine, bromine and sodium as well as their relation in connection with emission processes and photochemical activation in this unexplored area. A total of 32 surface (0–5 cm) and 32 bulk (average of 1 m depth) samples were taken and analysed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Our results show that there is no relevant latitudinal trend for bromine and sodium. For bromine they also show that it has no sig­nificant post-depositional mechanisms while its inland surface snow concentration is influenced by spring coastal bromine explosions. Iodine concentrations are several orders of magnitude lower than bromine and sodium and they show a decreasing trend in the surface samples concentration moving southward. This suggests that other processes affect its accumulation in surface snow, probably related to the radial reduction in the ozone layer moving towards central Antarctica. Even though all iodine, bromine and sodium present similar long-range transport from the dominant coastal Antarctic sources, the annual seasonal cycle of the ozone hole over Antarctica increases the amount of UV radiation (in the 280–320 nm range) reaching the surface, thereby affecting the surface snow photoactivation of iodine. A comparison between the bulk and surface samples supports the conclusion that iodine undergoes spring and summer snow recycling that increases its atmospheric lifetime, while it tends to accumulate during the winter months when photochemistry ceases.
Fil: Celli, G.. Ca’Foscari University of Venice; Italia
Fil: Cairns, W.R.L.. Ca’Foscari University of Venice; Italia. Consiglio Nazionale Delle Ricerche. Istituto Di Scienze Polari.; Italia
Fil: Scarchilli, C.. Università Roma Tre Iii. Dipartimento Di Scienze.; Italia
Fil: Cuevas, Carlos A.. Consejo Superior de Investigaciones Cientificas. Instituto de Quimica Fisica "rocasolano". Departamento de Quimica Atmosferica y Clima; España
Fil: Saiz López, Alfonso. Consejo Superior de Investigaciones Cientificas. Instituto de Quimica Fisica "rocasolano". Departamento de Quimica Atmosferica y Clima; España
Fil: Savarino, J.. Universite Grenoble Alpes.; Francia
Fil: Stenni, B.. Ca’Foscari University of Venice; Italia
Fil: Frezzotti, M.. Agenzia nazionale per le nuove tecnologie, l'energia e lo sviluppo económico sostenibile; Italia
Fil: Becagli, S.. Consiglio Nazionale Delle Ricerche. Istituto Di Scienze Polari.; Italia. Università degli Studi di Firenze; Italia
Fil: Delmonte, B.. Department Of Earth And Environmental Sciences (disat) ; Universita Degli Studi Di Milano;
Fil: Angot, H.. Universite Grenoble Alpes.; Francia
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina
Fil: Spolaor, Andrea. Consiglio Nazionale Delle Ricerche. Istituto Di Scienze Polari.; Italia
description During the East Antarctic International Ice Sheet Traverse (Eaiist, december 2019), in an unexplored part of the East Antarctic Plateau, snow samples were collected to expand our knowledge of the latitudinal variability of iodine, bromine and sodium as well as their relation in connection with emission processes and photochemical activation in this unexplored area. A total of 32 surface (0–5 cm) and 32 bulk (average of 1 m depth) samples were taken and analysed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Our results show that there is no relevant latitudinal trend for bromine and sodium. For bromine they also show that it has no sig­nificant post-depositional mechanisms while its inland surface snow concentration is influenced by spring coastal bromine explosions. Iodine concentrations are several orders of magnitude lower than bromine and sodium and they show a decreasing trend in the surface samples concentration moving southward. This suggests that other processes affect its accumulation in surface snow, probably related to the radial reduction in the ozone layer moving towards central Antarctica. Even though all iodine, bromine and sodium present similar long-range transport from the dominant coastal Antarctic sources, the annual seasonal cycle of the ozone hole over Antarctica increases the amount of UV radiation (in the 280–320 nm range) reaching the surface, thereby affecting the surface snow photoactivation of iodine. A comparison between the bulk and surface samples supports the conclusion that iodine undergoes spring and summer snow recycling that increases its atmospheric lifetime, while it tends to accumulate during the winter months when photochemistry ceases.
publishDate 2023
dc.date.none.fl_str_mv 2023-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/245079
Celli, G.; Cairns, W.R.L.; Scarchilli, C.; Cuevas, Carlos A.; Saiz López, Alfonso; et al.; Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability; Academic Press Inc Elsevier Science; Environmental Research; 239; 10-2023; 1-10
0013-9351
1096-0953
CONICET Digital
CONICET
url http://hdl.handle.net/11336/245079
identifier_str_mv Celli, G.; Cairns, W.R.L.; Scarchilli, C.; Cuevas, Carlos A.; Saiz López, Alfonso; et al.; Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability; Academic Press Inc Elsevier Science; Environmental Research; 239; 10-2023; 1-10
0013-9351
1096-0953
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0013935123021485
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.envres.2023.117344
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Academic Press Inc Elsevier Science
publisher.none.fl_str_mv Academic Press Inc Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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