Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments

Autores
Bia, Gonzalo Luis; Borgnino Bianchi, Laura Carolina; Gaiero, Diego Marcelo; Garcia, Maria Gabriela
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Three samples of volcanic ashes collected after eruptions of the volcanos Hudson in 1991, Chaitén in 2008 and Puyehue in 2011 were analyzed in order to define the solid speciation of arsenic and the dynamics of its release to the aqueous phase. The bulk chemical and mineralogical characterization of the samples was performed by ICP/OES, DRX, and SEM/EDS analyses. The chemical composition of the near surface region (first 2-10. nm), along with the As and Fe solid speciation was performed by XPS. Batch experiments were conducted to evaluate the kinetics of the arsenic release under variable pH conditions. The integrated analysis of these data indicates that arsenic compounds are concentrated onto the ash surface in the form of As(III)-S and As(V)-O species. The As(III) species have been assigned to arsenian pyrite, while As(V)-O compounds have been assigned to adsorbed arsenate ions or Fe arsenate salts precipitated as thin coatings.Although the main As carrier in the studied volcanic ashes is Al-silicate glass, this phase is stable at the neutral pH that dominates the aqueous reservoirs of the area affected by ashfall. Thus, its contribution to the pool of dissolved arsenic is minor. Higher contributions are clearly associated with the more mobile As species that concentrate onto the surface of Al-silicate glass. This more available arsenic represents less than 6% of the total measured arsenic.
Fil: Bia, Gonzalo Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Borgnino Bianchi, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Gaiero, Diego Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Garcia, Maria Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Materia
AL-SILICATE GLASS
AS SOLID SPECIATION
SOUTH AMERICA
XPS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/37629
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/37629
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environmentsBia, Gonzalo LuisBorgnino Bianchi, Laura CarolinaGaiero, Diego MarceloGarcia, Maria GabrielaAL-SILICATE GLASSAS SOLID SPECIATIONSOUTH AMERICAXPShttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Three samples of volcanic ashes collected after eruptions of the volcanos Hudson in 1991, Chaitén in 2008 and Puyehue in 2011 were analyzed in order to define the solid speciation of arsenic and the dynamics of its release to the aqueous phase. The bulk chemical and mineralogical characterization of the samples was performed by ICP/OES, DRX, and SEM/EDS analyses. The chemical composition of the near surface region (first 2-10. nm), along with the As and Fe solid speciation was performed by XPS. Batch experiments were conducted to evaluate the kinetics of the arsenic release under variable pH conditions. The integrated analysis of these data indicates that arsenic compounds are concentrated onto the ash surface in the form of As(III)-S and As(V)-O species. The As(III) species have been assigned to arsenian pyrite, while As(V)-O compounds have been assigned to adsorbed arsenate ions or Fe arsenate salts precipitated as thin coatings.Although the main As carrier in the studied volcanic ashes is Al-silicate glass, this phase is stable at the neutral pH that dominates the aqueous reservoirs of the area affected by ashfall. Thus, its contribution to the pool of dissolved arsenic is minor. Higher contributions are clearly associated with the more mobile As species that concentrate onto the surface of Al-silicate glass. This more available arsenic represents less than 6% of the total measured arsenic.Fil: Bia, Gonzalo Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Borgnino Bianchi, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Gaiero, Diego Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Garcia, Maria Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaElsevier Science2015-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/37629Bia, Gonzalo Luis; Borgnino Bianchi, Laura Carolina; Gaiero, Diego Marcelo; Garcia, Maria Gabriela; Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments; Elsevier Science; Chemical Geology; 393-394; 1-2015; 26-350009-2541CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemgeo.2014.10.007info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S000925411400446Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:39:41Zoai:ri.conicet.gov.ar:11336/37629instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:39:41.756CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments
title Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments
spellingShingle Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments
Bia, Gonzalo Luis
AL-SILICATE GLASS
AS SOLID SPECIATION
SOUTH AMERICA
XPS
title_short Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments
title_full Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments
title_fullStr Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments
title_full_unstemmed Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments
title_sort Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments
dc.creator.none.fl_str_mv Bia, Gonzalo Luis
Borgnino Bianchi, Laura Carolina
Gaiero, Diego Marcelo
Garcia, Maria Gabriela
author Bia, Gonzalo Luis
author_facet Bia, Gonzalo Luis
Borgnino Bianchi, Laura Carolina
Gaiero, Diego Marcelo
Garcia, Maria Gabriela
author_role author
author2 Borgnino Bianchi, Laura Carolina
Gaiero, Diego Marcelo
Garcia, Maria Gabriela
author2_role author
author
author
dc.subject.none.fl_str_mv AL-SILICATE GLASS
AS SOLID SPECIATION
SOUTH AMERICA
XPS
topic AL-SILICATE GLASS
AS SOLID SPECIATION
SOUTH AMERICA
XPS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Three samples of volcanic ashes collected after eruptions of the volcanos Hudson in 1991, Chaitén in 2008 and Puyehue in 2011 were analyzed in order to define the solid speciation of arsenic and the dynamics of its release to the aqueous phase. The bulk chemical and mineralogical characterization of the samples was performed by ICP/OES, DRX, and SEM/EDS analyses. The chemical composition of the near surface region (first 2-10. nm), along with the As and Fe solid speciation was performed by XPS. Batch experiments were conducted to evaluate the kinetics of the arsenic release under variable pH conditions. The integrated analysis of these data indicates that arsenic compounds are concentrated onto the ash surface in the form of As(III)-S and As(V)-O species. The As(III) species have been assigned to arsenian pyrite, while As(V)-O compounds have been assigned to adsorbed arsenate ions or Fe arsenate salts precipitated as thin coatings.Although the main As carrier in the studied volcanic ashes is Al-silicate glass, this phase is stable at the neutral pH that dominates the aqueous reservoirs of the area affected by ashfall. Thus, its contribution to the pool of dissolved arsenic is minor. Higher contributions are clearly associated with the more mobile As species that concentrate onto the surface of Al-silicate glass. This more available arsenic represents less than 6% of the total measured arsenic.
Fil: Bia, Gonzalo Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Borgnino Bianchi, Laura Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Gaiero, Diego Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Garcia, Maria Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
description Three samples of volcanic ashes collected after eruptions of the volcanos Hudson in 1991, Chaitén in 2008 and Puyehue in 2011 were analyzed in order to define the solid speciation of arsenic and the dynamics of its release to the aqueous phase. The bulk chemical and mineralogical characterization of the samples was performed by ICP/OES, DRX, and SEM/EDS analyses. The chemical composition of the near surface region (first 2-10. nm), along with the As and Fe solid speciation was performed by XPS. Batch experiments were conducted to evaluate the kinetics of the arsenic release under variable pH conditions. The integrated analysis of these data indicates that arsenic compounds are concentrated onto the ash surface in the form of As(III)-S and As(V)-O species. The As(III) species have been assigned to arsenian pyrite, while As(V)-O compounds have been assigned to adsorbed arsenate ions or Fe arsenate salts precipitated as thin coatings.Although the main As carrier in the studied volcanic ashes is Al-silicate glass, this phase is stable at the neutral pH that dominates the aqueous reservoirs of the area affected by ashfall. Thus, its contribution to the pool of dissolved arsenic is minor. Higher contributions are clearly associated with the more mobile As species that concentrate onto the surface of Al-silicate glass. This more available arsenic represents less than 6% of the total measured arsenic.
publishDate 2015
dc.date.none.fl_str_mv 2015-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/37629
Bia, Gonzalo Luis; Borgnino Bianchi, Laura Carolina; Gaiero, Diego Marcelo; Garcia, Maria Gabriela; Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments; Elsevier Science; Chemical Geology; 393-394; 1-2015; 26-35
0009-2541
CONICET Digital
CONICET
url http://hdl.handle.net/11336/37629
identifier_str_mv Bia, Gonzalo Luis; Borgnino Bianchi, Laura Carolina; Gaiero, Diego Marcelo; Garcia, Maria Gabriela; Arsenic-bearing phases in South Andean volcanic ashes: Implications for As mobility in aquatic environments; Elsevier Science; Chemical Geology; 393-394; 1-2015; 26-35
0009-2541
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.chemgeo.2014.10.007
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S000925411400446X
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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