Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication

Autores
Tamborini, Luciano Henri; Casco, Mirian E Lizabeth; Militello, María Paula; Silvestre Albero, J.; Barbero, César Alfredo; Acevedo, Diego Fernando
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Porous carbons (BSPCs) were obtained by carbonization of resorcinol-formaldehyde gels in the presence of cationic surfactants mixture (benzalkonium chloride) which act as porosity stabilizer. The application of an inexpensive industrial grade surfactant mixture as porosity stabilizer permits obtaining porous carbons with well-developed micro and mesoporosity at low cost. The stabilizing effect on the sol–gel nanostructure allows maintaining the gels porosity during conventional air drying, simplifying the production of porous carbon by making unnecessary complex drying procedures (e.g. supercritical drying), cumbersome solvent exchanges, and long curing times. The carbonization process of BSPCs studied by TGA shows that the stabilizer and non-carbon elements (hydrogen and oxygen) are only eliminated during pyrolysis at temperature above 600 °C. The BSPCs morphological and textural properties were studied by scanning electron microscopy and nitrogen physisorption isotherms. The BSPCs present large specific surface areas (up to 645 m2/g) containing mesopores and micropores. Furthermore, the pore distribution and morphology depend on the monomer (resorcinol) to stabilizer (benzalkonium chloride) ratio. Cyclic voltammetry and electrochemical impedance spectroscopy were employed to study the electrochemical properties of the carbon materials. The BSPCs exhibit a large specific capacitance (up to 179 F/g at 2.8 mHz in 1 M H2SO4) The results suggest that porosity stabilization of resorcinol/formaldehyde gels could be performed using different cationic surfactants, even commercial mixtures like benzalkonium chloride.
Fil: Tamborini, Luciano Henri. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Casco, Mirian E Lizabeth. Universidad de Alicante; España
Fil: Militello, María Paula. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Silvestre Albero, J.. Universidad de Alicante; España
Fil: Barbero, César Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Acevedo, Diego Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina
Materia
Commercial Surfactant Mixtures
Porous Carbon
Resorcinolformaldehyde
Soft Template
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/72350
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/72350
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabricationTamborini, Luciano HenriCasco, Mirian E LizabethMilitello, María PaulaSilvestre Albero, J.Barbero, César AlfredoAcevedo, Diego FernandoCommercial Surfactant MixturesPorous CarbonResorcinolformaldehydeSoft Templatehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Porous carbons (BSPCs) were obtained by carbonization of resorcinol-formaldehyde gels in the presence of cationic surfactants mixture (benzalkonium chloride) which act as porosity stabilizer. The application of an inexpensive industrial grade surfactant mixture as porosity stabilizer permits obtaining porous carbons with well-developed micro and mesoporosity at low cost. The stabilizing effect on the sol–gel nanostructure allows maintaining the gels porosity during conventional air drying, simplifying the production of porous carbon by making unnecessary complex drying procedures (e.g. supercritical drying), cumbersome solvent exchanges, and long curing times. The carbonization process of BSPCs studied by TGA shows that the stabilizer and non-carbon elements (hydrogen and oxygen) are only eliminated during pyrolysis at temperature above 600 °C. The BSPCs morphological and textural properties were studied by scanning electron microscopy and nitrogen physisorption isotherms. The BSPCs present large specific surface areas (up to 645 m2/g) containing mesopores and micropores. Furthermore, the pore distribution and morphology depend on the monomer (resorcinol) to stabilizer (benzalkonium chloride) ratio. Cyclic voltammetry and electrochemical impedance spectroscopy were employed to study the electrochemical properties of the carbon materials. The BSPCs exhibit a large specific capacitance (up to 179 F/g at 2.8 mHz in 1 M H2SO4) The results suggest that porosity stabilization of resorcinol/formaldehyde gels could be performed using different cationic surfactants, even commercial mixtures like benzalkonium chloride.Fil: Tamborini, Luciano Henri. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Casco, Mirian E Lizabeth. Universidad de Alicante; EspañaFil: Militello, María Paula. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Silvestre Albero, J.. Universidad de Alicante; EspañaFil: Barbero, César Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; ArgentinaFil: Acevedo, Diego Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; ArgentinaElsevier Science2016-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/72350Tamborini, Luciano Henri; Casco, Mirian E Lizabeth; Militello, María Paula; Silvestre Albero, J.; Barbero, César Alfredo; et al.; Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 509; 11-2016; 449-4560927-7757CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2016.09.020info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0927775716307695info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:53:17Zoai:ri.conicet.gov.ar:11336/72350instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:53:17.894CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication
title Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication
spellingShingle Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication
Tamborini, Luciano Henri
Commercial Surfactant Mixtures
Porous Carbon
Resorcinolformaldehyde
Soft Template
title_short Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication
title_full Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication
title_fullStr Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication
title_full_unstemmed Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication
title_sort Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication
dc.creator.none.fl_str_mv Tamborini, Luciano Henri
Casco, Mirian E Lizabeth
Militello, María Paula
Silvestre Albero, J.
Barbero, César Alfredo
Acevedo, Diego Fernando
author Tamborini, Luciano Henri
author_facet Tamborini, Luciano Henri
Casco, Mirian E Lizabeth
Militello, María Paula
Silvestre Albero, J.
Barbero, César Alfredo
Acevedo, Diego Fernando
author_role author
author2 Casco, Mirian E Lizabeth
Militello, María Paula
Silvestre Albero, J.
Barbero, César Alfredo
Acevedo, Diego Fernando
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Commercial Surfactant Mixtures
Porous Carbon
Resorcinolformaldehyde
Soft Template
topic Commercial Surfactant Mixtures
Porous Carbon
Resorcinolformaldehyde
Soft Template
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Porous carbons (BSPCs) were obtained by carbonization of resorcinol-formaldehyde gels in the presence of cationic surfactants mixture (benzalkonium chloride) which act as porosity stabilizer. The application of an inexpensive industrial grade surfactant mixture as porosity stabilizer permits obtaining porous carbons with well-developed micro and mesoporosity at low cost. The stabilizing effect on the sol–gel nanostructure allows maintaining the gels porosity during conventional air drying, simplifying the production of porous carbon by making unnecessary complex drying procedures (e.g. supercritical drying), cumbersome solvent exchanges, and long curing times. The carbonization process of BSPCs studied by TGA shows that the stabilizer and non-carbon elements (hydrogen and oxygen) are only eliminated during pyrolysis at temperature above 600 °C. The BSPCs morphological and textural properties were studied by scanning electron microscopy and nitrogen physisorption isotherms. The BSPCs present large specific surface areas (up to 645 m2/g) containing mesopores and micropores. Furthermore, the pore distribution and morphology depend on the monomer (resorcinol) to stabilizer (benzalkonium chloride) ratio. Cyclic voltammetry and electrochemical impedance spectroscopy were employed to study the electrochemical properties of the carbon materials. The BSPCs exhibit a large specific capacitance (up to 179 F/g at 2.8 mHz in 1 M H2SO4) The results suggest that porosity stabilization of resorcinol/formaldehyde gels could be performed using different cationic surfactants, even commercial mixtures like benzalkonium chloride.
Fil: Tamborini, Luciano Henri. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Casco, Mirian E Lizabeth. Universidad de Alicante; España
Fil: Militello, María Paula. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Silvestre Albero, J.. Universidad de Alicante; España
Fil: Barbero, César Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina
Fil: Acevedo, Diego Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba; Argentina. Universidad Nacional de Río Cuarto. Facultad de Ciencias Exactas Fisicoquímicas y Naturales. Departamento de Química; Argentina. Universidad Nacional de Rio Cuarto. Facultad de Ingeniería. Departamento de Tecnología Química; Argentina
description Porous carbons (BSPCs) were obtained by carbonization of resorcinol-formaldehyde gels in the presence of cationic surfactants mixture (benzalkonium chloride) which act as porosity stabilizer. The application of an inexpensive industrial grade surfactant mixture as porosity stabilizer permits obtaining porous carbons with well-developed micro and mesoporosity at low cost. The stabilizing effect on the sol–gel nanostructure allows maintaining the gels porosity during conventional air drying, simplifying the production of porous carbon by making unnecessary complex drying procedures (e.g. supercritical drying), cumbersome solvent exchanges, and long curing times. The carbonization process of BSPCs studied by TGA shows that the stabilizer and non-carbon elements (hydrogen and oxygen) are only eliminated during pyrolysis at temperature above 600 °C. The BSPCs morphological and textural properties were studied by scanning electron microscopy and nitrogen physisorption isotherms. The BSPCs present large specific surface areas (up to 645 m2/g) containing mesopores and micropores. Furthermore, the pore distribution and morphology depend on the monomer (resorcinol) to stabilizer (benzalkonium chloride) ratio. Cyclic voltammetry and electrochemical impedance spectroscopy were employed to study the electrochemical properties of the carbon materials. The BSPCs exhibit a large specific capacitance (up to 179 F/g at 2.8 mHz in 1 M H2SO4) The results suggest that porosity stabilization of resorcinol/formaldehyde gels could be performed using different cationic surfactants, even commercial mixtures like benzalkonium chloride.
publishDate 2016
dc.date.none.fl_str_mv 2016-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/72350
Tamborini, Luciano Henri; Casco, Mirian E Lizabeth; Militello, María Paula; Silvestre Albero, J.; Barbero, César Alfredo; et al.; Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 509; 11-2016; 449-456
0927-7757
CONICET Digital
CONICET
url http://hdl.handle.net/11336/72350
identifier_str_mv Tamborini, Luciano Henri; Casco, Mirian E Lizabeth; Militello, María Paula; Silvestre Albero, J.; Barbero, César Alfredo; et al.; Successful application of a commercial cationic surfactant mixture (benzalkonium chloride) as porosity stabilizer in porous carbons fabrication; Elsevier Science; Colloids and Surfaces A: Physicochemical and Engineering Aspects; 509; 11-2016; 449-456
0927-7757
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.colsurfa.2016.09.020
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0927775716307695
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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