Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F
- Autores
- Berasategui, Matias; Burgos Paci, Maximiliano Alberto; Argüello, Gustavo Alejandro
- Año de publicación
- 2011
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The synthesis of CH3OC(O)OOC(O)F is accomplished by the thermal reaction between CH3OH and FC(O)OOC(O)F at room temperature. The new peroxide is obtained in pure form after repeated trap-to-trap condensation and it is characterized by NMR and IR spectroscopy and mass spectrometry. Geometrical parameters were studied by ab initio methods [B3LYP/6-31++G(d,p)]. CH3OC(O)OOC(O)F isstable for a few hours at room temperature, and it decomposes into CO2, CO, HF, HC(O)OH, and CH2O. The boiling point is extrapolated to 366.5 K from the vapor pressure curve log p = 8.623–2061/T (p /mbar, T /K). The mechanisms for boththe formation and thermal decomposition of CH3OC(O)OOC(O)F are discussed, and some physicochemical properties are compared with those of related compounds.
Fil: Berasategui, Matias. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Burgos Paci, Maximiliano Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina
Fil: Argüello, Gustavo Alejandro. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina - Materia
- fluorinated compounds
- Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/271330
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3498 |
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CONICET Digital (CONICET) |
spelling |
Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)FBerasategui, MatiasBurgos Paci, Maximiliano AlbertoArgüello, Gustavo Alejandrofluorinated compoundshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The synthesis of CH3OC(O)OOC(O)F is accomplished by the thermal reaction between CH3OH and FC(O)OOC(O)F at room temperature. The new peroxide is obtained in pure form after repeated trap-to-trap condensation and it is characterized by NMR and IR spectroscopy and mass spectrometry. Geometrical parameters were studied by ab initio methods [B3LYP/6-31++G(d,p)]. CH3OC(O)OOC(O)F isstable for a few hours at room temperature, and it decomposes into CO2, CO, HF, HC(O)OH, and CH2O. The boiling point is extrapolated to 366.5 K from the vapor pressure curve log p = 8.623–2061/T (p /mbar, T /K). The mechanisms for boththe formation and thermal decomposition of CH3OC(O)OOC(O)F are discussed, and some physicochemical properties are compared with those of related compounds.Fil: Berasategui, Matias. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Burgos Paci, Maximiliano Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; ArgentinaFil: Argüello, Gustavo Alejandro. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaWiley VCH Verlag2011-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/271330Berasategui, Matias; Burgos Paci, Maximiliano Alberto; Argüello, Gustavo Alejandro; Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F; Wiley VCH Verlag; Zeitschrift Fur Anorganische Und Allgemeine Chemie; 638; 3-4; 12-2011; 547-5520044-2313CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/zaac.201100404info:eu-repo/semantics/altIdentifier/doi/10.1002/zaac.201100404info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:33:51Zoai:ri.conicet.gov.ar:11336/271330instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:33:52.196CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F |
title |
Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F |
spellingShingle |
Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F Berasategui, Matias fluorinated compounds |
title_short |
Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F |
title_full |
Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F |
title_fullStr |
Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F |
title_full_unstemmed |
Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F |
title_sort |
Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F |
dc.creator.none.fl_str_mv |
Berasategui, Matias Burgos Paci, Maximiliano Alberto Argüello, Gustavo Alejandro |
author |
Berasategui, Matias |
author_facet |
Berasategui, Matias Burgos Paci, Maximiliano Alberto Argüello, Gustavo Alejandro |
author_role |
author |
author2 |
Burgos Paci, Maximiliano Alberto Argüello, Gustavo Alejandro |
author2_role |
author author |
dc.subject.none.fl_str_mv |
fluorinated compounds |
topic |
fluorinated compounds |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The synthesis of CH3OC(O)OOC(O)F is accomplished by the thermal reaction between CH3OH and FC(O)OOC(O)F at room temperature. The new peroxide is obtained in pure form after repeated trap-to-trap condensation and it is characterized by NMR and IR spectroscopy and mass spectrometry. Geometrical parameters were studied by ab initio methods [B3LYP/6-31++G(d,p)]. CH3OC(O)OOC(O)F isstable for a few hours at room temperature, and it decomposes into CO2, CO, HF, HC(O)OH, and CH2O. The boiling point is extrapolated to 366.5 K from the vapor pressure curve log p = 8.623–2061/T (p /mbar, T /K). The mechanisms for boththe formation and thermal decomposition of CH3OC(O)OOC(O)F are discussed, and some physicochemical properties are compared with those of related compounds. Fil: Berasategui, Matias. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Burgos Paci, Maximiliano Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina Fil: Argüello, Gustavo Alejandro. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina |
description |
The synthesis of CH3OC(O)OOC(O)F is accomplished by the thermal reaction between CH3OH and FC(O)OOC(O)F at room temperature. The new peroxide is obtained in pure form after repeated trap-to-trap condensation and it is characterized by NMR and IR spectroscopy and mass spectrometry. Geometrical parameters were studied by ab initio methods [B3LYP/6-31++G(d,p)]. CH3OC(O)OOC(O)F isstable for a few hours at room temperature, and it decomposes into CO2, CO, HF, HC(O)OH, and CH2O. The boiling point is extrapolated to 366.5 K from the vapor pressure curve log p = 8.623–2061/T (p /mbar, T /K). The mechanisms for boththe formation and thermal decomposition of CH3OC(O)OOC(O)F are discussed, and some physicochemical properties are compared with those of related compounds. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/271330 Berasategui, Matias; Burgos Paci, Maximiliano Alberto; Argüello, Gustavo Alejandro; Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F; Wiley VCH Verlag; Zeitschrift Fur Anorganische Und Allgemeine Chemie; 638; 3-4; 12-2011; 547-552 0044-2313 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/271330 |
identifier_str_mv |
Berasategui, Matias; Burgos Paci, Maximiliano Alberto; Argüello, Gustavo Alejandro; Isolation and Characterization of CH 3 OC(O)OOC(O)F from the Reaction CH 3 OH + FC(O)OOC(O)F; Wiley VCH Verlag; Zeitschrift Fur Anorganische Und Allgemeine Chemie; 638; 3-4; 12-2011; 547-552 0044-2313 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/zaac.201100404 info:eu-repo/semantics/altIdentifier/doi/10.1002/zaac.201100404 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley VCH Verlag |
publisher.none.fl_str_mv |
Wiley VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614354410930176 |
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13.070432 |