Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite
- Autores
- Moreira Toja, Ramiro Julián; Rendtorff Birrer, Nicolás Maximiliano; Aglietti, Esteban Fausto; Uchikoshi, Tetsuo; Sakka, Yoshio; Suarez, Gustavo
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Lanthanum silicate oxyapatite (LSO) is an encouraging material for its use as an electrolyte in intermediate temperature solid oxide fuel cells. There is a vacancy in knowledge respecting to LSO's mechanical properties, and thus they are the scope of research of the present work. Isostatically pressed bars were sintered at temperatures from 1200 °C to 1500 °C. The dependence of Young's modulus with porosity was fitted using three different modeling curves, and extrapolated for a fully dense material. The fitting of these equations give an E0 between 144 GPa and 169 GPa. This is the first time that LSO's Young's modulus is reported. Flexural strength,Vickers hardness, fracture toughness (KIC) from microindentation cracks and nanohardness were also measured. Scanning electron micrography was performed on both a sub-sintered and the most sintered sample, and the microstructure and fracture mechanism were analyzed. In general, the mechanical behaviour is similar to other intermediate temperature solid oxide electrolytes. The fracture mechanism of the most sintered sample makes it well-suited for future SOFC applications.
Fil: Moreira Toja, Ramiro Julián. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Rendtorff Birrer, Nicolás Maximiliano. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Aglietti, Esteban Fausto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina
Fil: Uchikoshi, Tetsuo. Tsukuba University. National Institute For Materials Science; Japón
Fil: Sakka, Yoshio. Tsukuba University. National Institute For Materials Science; Japón
Fil: Suarez, Gustavo. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina - Materia
-
Lanthanum silicate oxyapatite
Mechanical properties
Young's modulus
Fracture - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/95479
Ver los metadatos del registro completo
id |
CONICETDig_02453517e0d97fe14d81f34685aed5da |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/95479 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatiteMoreira Toja, Ramiro JuliánRendtorff Birrer, Nicolás MaximilianoAglietti, Esteban FaustoUchikoshi, TetsuoSakka, YoshioSuarez, GustavoLanthanum silicate oxyapatiteMechanical propertiesYoung's modulusFracturehttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Lanthanum silicate oxyapatite (LSO) is an encouraging material for its use as an electrolyte in intermediate temperature solid oxide fuel cells. There is a vacancy in knowledge respecting to LSO's mechanical properties, and thus they are the scope of research of the present work. Isostatically pressed bars were sintered at temperatures from 1200 °C to 1500 °C. The dependence of Young's modulus with porosity was fitted using three different modeling curves, and extrapolated for a fully dense material. The fitting of these equations give an E0 between 144 GPa and 169 GPa. This is the first time that LSO's Young's modulus is reported. Flexural strength,Vickers hardness, fracture toughness (KIC) from microindentation cracks and nanohardness were also measured. Scanning electron micrography was performed on both a sub-sintered and the most sintered sample, and the microstructure and fracture mechanism were analyzed. In general, the mechanical behaviour is similar to other intermediate temperature solid oxide electrolytes. The fracture mechanism of the most sintered sample makes it well-suited for future SOFC applications.Fil: Moreira Toja, Ramiro Julián. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Rendtorff Birrer, Nicolás Maximiliano. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Aglietti, Esteban Fausto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaFil: Uchikoshi, Tetsuo. Tsukuba University. National Institute For Materials Science; JapónFil: Sakka, Yoshio. Tsukuba University. National Institute For Materials Science; JapónFil: Suarez, Gustavo. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; ArgentinaElsevier2018-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/95479Moreira Toja, Ramiro Julián; Rendtorff Birrer, Nicolás Maximiliano; Aglietti, Esteban Fausto; Uchikoshi, Tetsuo; Sakka, Yoshio; et al.; Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite; Elsevier; Ceramics International; 44; 12; 8-2018; 14348-143540272-8842CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S027288421831174Xinfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2018.05.043info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:38:23Zoai:ri.conicet.gov.ar:11336/95479instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:38:23.729CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite |
title |
Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite |
spellingShingle |
Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite Moreira Toja, Ramiro Julián Lanthanum silicate oxyapatite Mechanical properties Young's modulus Fracture |
title_short |
Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite |
title_full |
Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite |
title_fullStr |
Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite |
title_full_unstemmed |
Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite |
title_sort |
Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite |
dc.creator.none.fl_str_mv |
Moreira Toja, Ramiro Julián Rendtorff Birrer, Nicolás Maximiliano Aglietti, Esteban Fausto Uchikoshi, Tetsuo Sakka, Yoshio Suarez, Gustavo |
author |
Moreira Toja, Ramiro Julián |
author_facet |
Moreira Toja, Ramiro Julián Rendtorff Birrer, Nicolás Maximiliano Aglietti, Esteban Fausto Uchikoshi, Tetsuo Sakka, Yoshio Suarez, Gustavo |
author_role |
author |
author2 |
Rendtorff Birrer, Nicolás Maximiliano Aglietti, Esteban Fausto Uchikoshi, Tetsuo Sakka, Yoshio Suarez, Gustavo |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Lanthanum silicate oxyapatite Mechanical properties Young's modulus Fracture |
topic |
Lanthanum silicate oxyapatite Mechanical properties Young's modulus Fracture |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Lanthanum silicate oxyapatite (LSO) is an encouraging material for its use as an electrolyte in intermediate temperature solid oxide fuel cells. There is a vacancy in knowledge respecting to LSO's mechanical properties, and thus they are the scope of research of the present work. Isostatically pressed bars were sintered at temperatures from 1200 °C to 1500 °C. The dependence of Young's modulus with porosity was fitted using three different modeling curves, and extrapolated for a fully dense material. The fitting of these equations give an E0 between 144 GPa and 169 GPa. This is the first time that LSO's Young's modulus is reported. Flexural strength,Vickers hardness, fracture toughness (KIC) from microindentation cracks and nanohardness were also measured. Scanning electron micrography was performed on both a sub-sintered and the most sintered sample, and the microstructure and fracture mechanism were analyzed. In general, the mechanical behaviour is similar to other intermediate temperature solid oxide electrolytes. The fracture mechanism of the most sintered sample makes it well-suited for future SOFC applications. Fil: Moreira Toja, Ramiro Julián. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina Fil: Rendtorff Birrer, Nicolás Maximiliano. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina Fil: Aglietti, Esteban Fausto. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina Fil: Uchikoshi, Tetsuo. Tsukuba University. National Institute For Materials Science; Japón Fil: Sakka, Yoshio. Tsukuba University. National Institute For Materials Science; Japón Fil: Suarez, Gustavo. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Departamento de Química; Argentina. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Tecnología de Recursos Minerales y Cerámica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Tecnología de Recursos Minerales y Cerámica; Argentina |
description |
Lanthanum silicate oxyapatite (LSO) is an encouraging material for its use as an electrolyte in intermediate temperature solid oxide fuel cells. There is a vacancy in knowledge respecting to LSO's mechanical properties, and thus they are the scope of research of the present work. Isostatically pressed bars were sintered at temperatures from 1200 °C to 1500 °C. The dependence of Young's modulus with porosity was fitted using three different modeling curves, and extrapolated for a fully dense material. The fitting of these equations give an E0 between 144 GPa and 169 GPa. This is the first time that LSO's Young's modulus is reported. Flexural strength,Vickers hardness, fracture toughness (KIC) from microindentation cracks and nanohardness were also measured. Scanning electron micrography was performed on both a sub-sintered and the most sintered sample, and the microstructure and fracture mechanism were analyzed. In general, the mechanical behaviour is similar to other intermediate temperature solid oxide electrolytes. The fracture mechanism of the most sintered sample makes it well-suited for future SOFC applications. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-08 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/95479 Moreira Toja, Ramiro Julián; Rendtorff Birrer, Nicolás Maximiliano; Aglietti, Esteban Fausto; Uchikoshi, Tetsuo; Sakka, Yoshio; et al.; Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite; Elsevier; Ceramics International; 44; 12; 8-2018; 14348-14354 0272-8842 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/95479 |
identifier_str_mv |
Moreira Toja, Ramiro Julián; Rendtorff Birrer, Nicolás Maximiliano; Aglietti, Esteban Fausto; Uchikoshi, Tetsuo; Sakka, Yoshio; et al.; Influence of the porosity caused by incomplete sintering on the mechanical behaviour of lanthanum silicate oxyapatite; Elsevier; Ceramics International; 44; 12; 8-2018; 14348-14354 0272-8842 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S027288421831174X info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceramint.2018.05.043 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844613212883910656 |
score |
13.070432 |