Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride

Autores
Mirenda, Martin; Rodrigues Ferreira Maltez, Dario Pablo; Arenillas, Pablo; Gutkowski, Karin
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report the detection of the Čerenkov luminescence after the incorporation of a few droplets of a physiological solution of 2-deoxi-2(18F)fluorine-d-glucose into the ionic liquid 1-Butyl-3-Methylimidazolium Chloride (BmimCl). The phenomenon is attributed to the β+ particles having energy above the threshold energy value for the Čerenkov radiation in this medium. The presence of another type of radiation that could eventually cause coincidences in the photodetectors was safely discarded. We show that this property serves to determine the activity of a 18F solution by means of the novel TDCR–Čerenkov technique. The results were compared with those obtained from the classic TDCR scintillation method using a commercial scintillation cocktail. The activity values obtained from both methods were found to be virtually identical within the experimental uncertainties. The fact that high energy β particles in BmimCl generates Čerenkov photons makes this ionic liquid a promising compound for future research in detection and quantification of ionizing radiation, and it provides a potential alternative for applications in nuclear technology.
Fil: Mirenda, Martin. Comisión Nacional de Energía Atómica. Gerencia Química. CAC; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Rodrigues Ferreira Maltez, Dario Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia Física (Centro Atómico Constituyentes). Proyecto Tandar; Argentina
Fil: Arenillas, Pablo. Comisión Nacional de Energía Atómica. Centro Atómico Ezeiza; Argentina
Fil: Gutkowski, Karin. Comisión Nacional de Energía Atómica. Gerencia Química. CAC; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Ionic Liquids
1-Butyl-3-Methylimidazolium Chloride
Cerenkov
Tdcr-Method
Ionizing Radiation Detection
Tdcr–Čerenkov Method
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/33655
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium ChlorideMirenda, MartinRodrigues Ferreira Maltez, Dario PabloArenillas, PabloGutkowski, KarinIonic Liquids1-Butyl-3-Methylimidazolium ChlorideCerenkovTdcr-MethodIonizing Radiation DetectionTdcr–Čerenkov Methodhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1We report the detection of the Čerenkov luminescence after the incorporation of a few droplets of a physiological solution of 2-deoxi-2(18F)fluorine-d-glucose into the ionic liquid 1-Butyl-3-Methylimidazolium Chloride (BmimCl). The phenomenon is attributed to the β+ particles having energy above the threshold energy value for the Čerenkov radiation in this medium. The presence of another type of radiation that could eventually cause coincidences in the photodetectors was safely discarded. We show that this property serves to determine the activity of a 18F solution by means of the novel TDCR–Čerenkov technique. The results were compared with those obtained from the classic TDCR scintillation method using a commercial scintillation cocktail. The activity values obtained from both methods were found to be virtually identical within the experimental uncertainties. The fact that high energy β particles in BmimCl generates Čerenkov photons makes this ionic liquid a promising compound for future research in detection and quantification of ionizing radiation, and it provides a potential alternative for applications in nuclear technology.Fil: Mirenda, Martin. Comisión Nacional de Energía Atómica. Gerencia Química. CAC; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Rodrigues Ferreira Maltez, Dario Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia Física (Centro Atómico Constituyentes). Proyecto Tandar; ArgentinaFil: Arenillas, Pablo. Comisión Nacional de Energía Atómica. Centro Atómico Ezeiza; ArgentinaFil: Gutkowski, Karin. Comisión Nacional de Energía Atómica. Gerencia Química. CAC; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElsevier2014-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/33655Gutkowski, Karin; Rodrigues Ferreira Maltez, Dario Pablo; Mirenda, Martin; Arenillas, Pablo; Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride; Elsevier; Radiation Physics and Chemistry (Oxford); 98; 1-2014; 98-1020969-806XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.radphyschem.2014.01.010info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0969806X14000140info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:45:26Zoai:ri.conicet.gov.ar:11336/33655instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:45:26.699CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride
title Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride
spellingShingle Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride
Mirenda, Martin
Ionic Liquids
1-Butyl-3-Methylimidazolium Chloride
Cerenkov
Tdcr-Method
Ionizing Radiation Detection
Tdcr–Čerenkov Method
title_short Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride
title_full Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride
title_fullStr Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride
title_full_unstemmed Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride
title_sort Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride
dc.creator.none.fl_str_mv Mirenda, Martin
Rodrigues Ferreira Maltez, Dario Pablo
Arenillas, Pablo
Gutkowski, Karin
author Mirenda, Martin
author_facet Mirenda, Martin
Rodrigues Ferreira Maltez, Dario Pablo
Arenillas, Pablo
Gutkowski, Karin
author_role author
author2 Rodrigues Ferreira Maltez, Dario Pablo
Arenillas, Pablo
Gutkowski, Karin
author2_role author
author
author
dc.subject.none.fl_str_mv Ionic Liquids
1-Butyl-3-Methylimidazolium Chloride
Cerenkov
Tdcr-Method
Ionizing Radiation Detection
Tdcr–Čerenkov Method
topic Ionic Liquids
1-Butyl-3-Methylimidazolium Chloride
Cerenkov
Tdcr-Method
Ionizing Radiation Detection
Tdcr–Čerenkov Method
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We report the detection of the Čerenkov luminescence after the incorporation of a few droplets of a physiological solution of 2-deoxi-2(18F)fluorine-d-glucose into the ionic liquid 1-Butyl-3-Methylimidazolium Chloride (BmimCl). The phenomenon is attributed to the β+ particles having energy above the threshold energy value for the Čerenkov radiation in this medium. The presence of another type of radiation that could eventually cause coincidences in the photodetectors was safely discarded. We show that this property serves to determine the activity of a 18F solution by means of the novel TDCR–Čerenkov technique. The results were compared with those obtained from the classic TDCR scintillation method using a commercial scintillation cocktail. The activity values obtained from both methods were found to be virtually identical within the experimental uncertainties. The fact that high energy β particles in BmimCl generates Čerenkov photons makes this ionic liquid a promising compound for future research in detection and quantification of ionizing radiation, and it provides a potential alternative for applications in nuclear technology.
Fil: Mirenda, Martin. Comisión Nacional de Energía Atómica. Gerencia Química. CAC; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Química Inorgánica, Analítica y Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Rodrigues Ferreira Maltez, Dario Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia Física (Centro Atómico Constituyentes). Proyecto Tandar; Argentina
Fil: Arenillas, Pablo. Comisión Nacional de Energía Atómica. Centro Atómico Ezeiza; Argentina
Fil: Gutkowski, Karin. Comisión Nacional de Energía Atómica. Gerencia Química. CAC; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description We report the detection of the Čerenkov luminescence after the incorporation of a few droplets of a physiological solution of 2-deoxi-2(18F)fluorine-d-glucose into the ionic liquid 1-Butyl-3-Methylimidazolium Chloride (BmimCl). The phenomenon is attributed to the β+ particles having energy above the threshold energy value for the Čerenkov radiation in this medium. The presence of another type of radiation that could eventually cause coincidences in the photodetectors was safely discarded. We show that this property serves to determine the activity of a 18F solution by means of the novel TDCR–Čerenkov technique. The results were compared with those obtained from the classic TDCR scintillation method using a commercial scintillation cocktail. The activity values obtained from both methods were found to be virtually identical within the experimental uncertainties. The fact that high energy β particles in BmimCl generates Čerenkov photons makes this ionic liquid a promising compound for future research in detection and quantification of ionizing radiation, and it provides a potential alternative for applications in nuclear technology.
publishDate 2014
dc.date.none.fl_str_mv 2014-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/33655
Gutkowski, Karin; Rodrigues Ferreira Maltez, Dario Pablo; Mirenda, Martin; Arenillas, Pablo; Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride; Elsevier; Radiation Physics and Chemistry (Oxford); 98; 1-2014; 98-102
0969-806X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/33655
identifier_str_mv Gutkowski, Karin; Rodrigues Ferreira Maltez, Dario Pablo; Mirenda, Martin; Arenillas, Pablo; Ionic liquids as solvents for liquid scintillation technology: Čerenkov counting with 1-Butyl-3-Methylimidazolium Chloride; Elsevier; Radiation Physics and Chemistry (Oxford); 98; 1-2014; 98-102
0969-806X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.radphyschem.2014.01.010
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0969806X14000140
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842268731705655296
score 13.13397

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