Scaling behavior of adsorption on patchwise bivariate surfaces revisited
- Autores
- Bulnes, Fernando Manuel; Ramirez Pastor, Antonio Jose; Zgrablich, Jorge Andres
- Año de publicación
- 2007
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The adsorption of gases on patchwise heterogeneous bivariate surfaces is studied. These surfaces are characterized by a collection of strong and weak adsorbing patches with a typical length scale l. Different forms and spatial arrangements of these patches determine different topographies characterized by an effective length, leff = σl, where σ takes values from 1 to 4 for the different topographies considered here. Previous studies showed that the mean square deviation between isotherms corresponding to different values of leff scaled as a power law with exponent α, without providing any physical interpretation of such behavior. In the present work, we introduce a different scaling function, χ(l), which is shown to be twice the difference in free energy per site between a reference isotherm and the given isotherm, at half coverage. With this function the scaling behavior and the value of the scaling exponent α are determined over the whole range of interparticles interaction energy and adsorptive energy, and for different temperatures, through Monte Carlo simulations. The results are similar to those obtained in previous studies, with a value of α which is half the one obtained before due to the different definition of the scaling function, but the present analysis provides a full understanding of the scaling behavior based on the physical significance of the scaling function and the scaling exponent.
Fil: Bulnes, Fernando Manuel. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina
Fil: Ramirez Pastor, Antonio Jose. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina
Fil: Zgrablich, Jorge Andres. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina - Materia
-
Adsorption
Lattice gas
Heterogeneity
Correlation - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/147771
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Scaling behavior of adsorption on patchwise bivariate surfaces revisitedBulnes, Fernando ManuelRamirez Pastor, Antonio JoseZgrablich, Jorge AndresAdsorptionLattice gasHeterogeneityCorrelationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The adsorption of gases on patchwise heterogeneous bivariate surfaces is studied. These surfaces are characterized by a collection of strong and weak adsorbing patches with a typical length scale l. Different forms and spatial arrangements of these patches determine different topographies characterized by an effective length, leff = σl, where σ takes values from 1 to 4 for the different topographies considered here. Previous studies showed that the mean square deviation between isotherms corresponding to different values of leff scaled as a power law with exponent α, without providing any physical interpretation of such behavior. In the present work, we introduce a different scaling function, χ(l), which is shown to be twice the difference in free energy per site between a reference isotherm and the given isotherm, at half coverage. With this function the scaling behavior and the value of the scaling exponent α are determined over the whole range of interparticles interaction energy and adsorptive energy, and for different temperatures, through Monte Carlo simulations. The results are similar to those obtained in previous studies, with a value of α which is half the one obtained before due to the different definition of the scaling function, but the present analysis provides a full understanding of the scaling behavior based on the physical significance of the scaling function and the scaling exponent.Fil: Bulnes, Fernando Manuel. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; ArgentinaFil: Ramirez Pastor, Antonio Jose. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; ArgentinaFil: Zgrablich, Jorge Andres. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; ArgentinaAmerican Chemical Society2007-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/147771Bulnes, Fernando Manuel; Ramirez Pastor, Antonio Jose; Zgrablich, Jorge Andres; Scaling behavior of adsorption on patchwise bivariate surfaces revisited; American Chemical Society; Langmuir; 23; 3; 1-2007; 1264-12690743-74631520-5827CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/la062491sinfo:eu-repo/semantics/altIdentifier/doi/10.1021/la062491sinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:44:19Zoai:ri.conicet.gov.ar:11336/147771instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:44:19.37CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Scaling behavior of adsorption on patchwise bivariate surfaces revisited |
title |
Scaling behavior of adsorption on patchwise bivariate surfaces revisited |
spellingShingle |
Scaling behavior of adsorption on patchwise bivariate surfaces revisited Bulnes, Fernando Manuel Adsorption Lattice gas Heterogeneity Correlation |
title_short |
Scaling behavior of adsorption on patchwise bivariate surfaces revisited |
title_full |
Scaling behavior of adsorption on patchwise bivariate surfaces revisited |
title_fullStr |
Scaling behavior of adsorption on patchwise bivariate surfaces revisited |
title_full_unstemmed |
Scaling behavior of adsorption on patchwise bivariate surfaces revisited |
title_sort |
Scaling behavior of adsorption on patchwise bivariate surfaces revisited |
dc.creator.none.fl_str_mv |
Bulnes, Fernando Manuel Ramirez Pastor, Antonio Jose Zgrablich, Jorge Andres |
author |
Bulnes, Fernando Manuel |
author_facet |
Bulnes, Fernando Manuel Ramirez Pastor, Antonio Jose Zgrablich, Jorge Andres |
author_role |
author |
author2 |
Ramirez Pastor, Antonio Jose Zgrablich, Jorge Andres |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Adsorption Lattice gas Heterogeneity Correlation |
topic |
Adsorption Lattice gas Heterogeneity Correlation |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The adsorption of gases on patchwise heterogeneous bivariate surfaces is studied. These surfaces are characterized by a collection of strong and weak adsorbing patches with a typical length scale l. Different forms and spatial arrangements of these patches determine different topographies characterized by an effective length, leff = σl, where σ takes values from 1 to 4 for the different topographies considered here. Previous studies showed that the mean square deviation between isotherms corresponding to different values of leff scaled as a power law with exponent α, without providing any physical interpretation of such behavior. In the present work, we introduce a different scaling function, χ(l), which is shown to be twice the difference in free energy per site between a reference isotherm and the given isotherm, at half coverage. With this function the scaling behavior and the value of the scaling exponent α are determined over the whole range of interparticles interaction energy and adsorptive energy, and for different temperatures, through Monte Carlo simulations. The results are similar to those obtained in previous studies, with a value of α which is half the one obtained before due to the different definition of the scaling function, but the present analysis provides a full understanding of the scaling behavior based on the physical significance of the scaling function and the scaling exponent. Fil: Bulnes, Fernando Manuel. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina Fil: Ramirez Pastor, Antonio Jose. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina Fil: Zgrablich, Jorge Andres. Universidad Nacional de San Luis. Facultad de Ciencias Fisico Matematicas y Naturales. Departamento de Fisica. Laboratorio de Ciencias de Superficies y Medios Porosos; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis; Argentina |
description |
The adsorption of gases on patchwise heterogeneous bivariate surfaces is studied. These surfaces are characterized by a collection of strong and weak adsorbing patches with a typical length scale l. Different forms and spatial arrangements of these patches determine different topographies characterized by an effective length, leff = σl, where σ takes values from 1 to 4 for the different topographies considered here. Previous studies showed that the mean square deviation between isotherms corresponding to different values of leff scaled as a power law with exponent α, without providing any physical interpretation of such behavior. In the present work, we introduce a different scaling function, χ(l), which is shown to be twice the difference in free energy per site between a reference isotherm and the given isotherm, at half coverage. With this function the scaling behavior and the value of the scaling exponent α are determined over the whole range of interparticles interaction energy and adsorptive energy, and for different temperatures, through Monte Carlo simulations. The results are similar to those obtained in previous studies, with a value of α which is half the one obtained before due to the different definition of the scaling function, but the present analysis provides a full understanding of the scaling behavior based on the physical significance of the scaling function and the scaling exponent. |
publishDate |
2007 |
dc.date.none.fl_str_mv |
2007-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/147771 Bulnes, Fernando Manuel; Ramirez Pastor, Antonio Jose; Zgrablich, Jorge Andres; Scaling behavior of adsorption on patchwise bivariate surfaces revisited; American Chemical Society; Langmuir; 23; 3; 1-2007; 1264-1269 0743-7463 1520-5827 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/147771 |
identifier_str_mv |
Bulnes, Fernando Manuel; Ramirez Pastor, Antonio Jose; Zgrablich, Jorge Andres; Scaling behavior of adsorption on patchwise bivariate surfaces revisited; American Chemical Society; Langmuir; 23; 3; 1-2007; 1264-1269 0743-7463 1520-5827 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/la062491s info:eu-repo/semantics/altIdentifier/doi/10.1021/la062491s |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
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Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613395227082752 |
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13.070432 |