Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina

Autores
Hughes, Enrique Alejandro; Zalts, Anita; Ojeda, Javier J.; Flores, Andrea P.; Glass, Richard C.; Montserrat, Javier Marcelo
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
An analytical method has been developed that can be used to determine the potential dermal exposure (PDE) of workers to the pesticide captan in small-scale horticultural production units. The methodology is based on the whole body dosimetry technique, using a cotton coverall and cotton gloves as sampling media, with protective clothing worn beneath the cotton media to protect the operator. The quantitative determination of captan was done by gas chromatography-electron capture detector (GC-ECD), with the analytical method validated by measuring limits of detection and quantification, linear ranges, sample recovery and precision. Special emphasis is placed on factors that affected the stability of captan during chromatographic determination. The data generated for potential dermal exposure are presented separately for mixing/loading and application activities. These data are compared with values obtained with visible tracers using a similar field technique. Margin of safety (MOS) values are also calculated for the agricultural procedures studied.
Fil: Hughes, Enrique Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Zalts, Anita. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Ojeda, Javier J.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Flores, Andrea P.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Glass, Richard C.. Food and Rural Affairs; Estados Unidos
Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Materia
Captan
Gc-Ecd
Periurban Agriculture
Potential Dermal Exposure
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/79896
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/79896
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in ArgentinaHughes, Enrique AlejandroZalts, AnitaOjeda, Javier J.Flores, Andrea P.Glass, Richard C.Montserrat, Javier MarceloCaptanGc-EcdPeriurban AgriculturePotential Dermal Exposurehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1An analytical method has been developed that can be used to determine the potential dermal exposure (PDE) of workers to the pesticide captan in small-scale horticultural production units. The methodology is based on the whole body dosimetry technique, using a cotton coverall and cotton gloves as sampling media, with protective clothing worn beneath the cotton media to protect the operator. The quantitative determination of captan was done by gas chromatography-electron capture detector (GC-ECD), with the analytical method validated by measuring limits of detection and quantification, linear ranges, sample recovery and precision. Special emphasis is placed on factors that affected the stability of captan during chromatographic determination. The data generated for potential dermal exposure are presented separately for mixing/loading and application activities. These data are compared with values obtained with visible tracers using a similar field technique. Margin of safety (MOS) values are also calculated for the agricultural procedures studied.Fil: Hughes, Enrique Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Zalts, Anita. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Ojeda, Javier J.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Flores, Andrea P.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Glass, Richard C.. Food and Rural Affairs; Estados UnidosFil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaJohn Wiley & Sons Ltd2006-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/79896Hughes, Enrique Alejandro; Zalts, Anita; Ojeda, Javier J.; Flores, Andrea P.; Glass, Richard C.; et al.; Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina; John Wiley & Sons Ltd; Pest Management Science; 62; 9; 9-2006; 811-8181526-498XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ps.1232info:eu-repo/semantics/altIdentifier/doi/10.1002/ps.1232info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:35:20Zoai:ri.conicet.gov.ar:11336/79896instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:35:20.544CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina
title Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina
spellingShingle Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina
Hughes, Enrique Alejandro
Captan
Gc-Ecd
Periurban Agriculture
Potential Dermal Exposure
title_short Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina
title_full Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina
title_fullStr Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina
title_full_unstemmed Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina
title_sort Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina
dc.creator.none.fl_str_mv Hughes, Enrique Alejandro
Zalts, Anita
Ojeda, Javier J.
Flores, Andrea P.
Glass, Richard C.
Montserrat, Javier Marcelo
author Hughes, Enrique Alejandro
author_facet Hughes, Enrique Alejandro
Zalts, Anita
Ojeda, Javier J.
Flores, Andrea P.
Glass, Richard C.
Montserrat, Javier Marcelo
author_role author
author2 Zalts, Anita
Ojeda, Javier J.
Flores, Andrea P.
Glass, Richard C.
Montserrat, Javier Marcelo
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Captan
Gc-Ecd
Periurban Agriculture
Potential Dermal Exposure
topic Captan
Gc-Ecd
Periurban Agriculture
Potential Dermal Exposure
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv An analytical method has been developed that can be used to determine the potential dermal exposure (PDE) of workers to the pesticide captan in small-scale horticultural production units. The methodology is based on the whole body dosimetry technique, using a cotton coverall and cotton gloves as sampling media, with protective clothing worn beneath the cotton media to protect the operator. The quantitative determination of captan was done by gas chromatography-electron capture detector (GC-ECD), with the analytical method validated by measuring limits of detection and quantification, linear ranges, sample recovery and precision. Special emphasis is placed on factors that affected the stability of captan during chromatographic determination. The data generated for potential dermal exposure are presented separately for mixing/loading and application activities. These data are compared with values obtained with visible tracers using a similar field technique. Margin of safety (MOS) values are also calculated for the agricultural procedures studied.
Fil: Hughes, Enrique Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Zalts, Anita. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Ojeda, Javier J.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Flores, Andrea P.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Glass, Richard C.. Food and Rural Affairs; Estados Unidos
Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
description An analytical method has been developed that can be used to determine the potential dermal exposure (PDE) of workers to the pesticide captan in small-scale horticultural production units. The methodology is based on the whole body dosimetry technique, using a cotton coverall and cotton gloves as sampling media, with protective clothing worn beneath the cotton media to protect the operator. The quantitative determination of captan was done by gas chromatography-electron capture detector (GC-ECD), with the analytical method validated by measuring limits of detection and quantification, linear ranges, sample recovery and precision. Special emphasis is placed on factors that affected the stability of captan during chromatographic determination. The data generated for potential dermal exposure are presented separately for mixing/loading and application activities. These data are compared with values obtained with visible tracers using a similar field technique. Margin of safety (MOS) values are also calculated for the agricultural procedures studied.
publishDate 2006
dc.date.none.fl_str_mv 2006-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/79896
Hughes, Enrique Alejandro; Zalts, Anita; Ojeda, Javier J.; Flores, Andrea P.; Glass, Richard C.; et al.; Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina; John Wiley & Sons Ltd; Pest Management Science; 62; 9; 9-2006; 811-818
1526-498X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/79896
identifier_str_mv Hughes, Enrique Alejandro; Zalts, Anita; Ojeda, Javier J.; Flores, Andrea P.; Glass, Richard C.; et al.; Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina; John Wiley & Sons Ltd; Pest Management Science; 62; 9; 9-2006; 811-818
1526-498X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ps.1232
info:eu-repo/semantics/altIdentifier/doi/10.1002/ps.1232
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614371177660416
score 13.070432

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