Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina
- Autores
- Hughes, Enrique Alejandro; Zalts, Anita; Ojeda, Javier J.; Flores, Andrea P.; Glass, Richard C.; Montserrat, Javier Marcelo
- Año de publicación
- 2006
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- An analytical method has been developed that can be used to determine the potential dermal exposure (PDE) of workers to the pesticide captan in small-scale horticultural production units. The methodology is based on the whole body dosimetry technique, using a cotton coverall and cotton gloves as sampling media, with protective clothing worn beneath the cotton media to protect the operator. The quantitative determination of captan was done by gas chromatography-electron capture detector (GC-ECD), with the analytical method validated by measuring limits of detection and quantification, linear ranges, sample recovery and precision. Special emphasis is placed on factors that affected the stability of captan during chromatographic determination. The data generated for potential dermal exposure are presented separately for mixing/loading and application activities. These data are compared with values obtained with visible tracers using a similar field technique. Margin of safety (MOS) values are also calculated for the agricultural procedures studied.
Fil: Hughes, Enrique Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Zalts, Anita. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Ojeda, Javier J.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Flores, Andrea P.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina
Fil: Glass, Richard C.. Food and Rural Affairs; Estados Unidos
Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina - Materia
-
Captan
Gc-Ecd
Periurban Agriculture
Potential Dermal Exposure - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/79896
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spelling |
Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in ArgentinaHughes, Enrique AlejandroZalts, AnitaOjeda, Javier J.Flores, Andrea P.Glass, Richard C.Montserrat, Javier MarceloCaptanGc-EcdPeriurban AgriculturePotential Dermal Exposurehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1An analytical method has been developed that can be used to determine the potential dermal exposure (PDE) of workers to the pesticide captan in small-scale horticultural production units. The methodology is based on the whole body dosimetry technique, using a cotton coverall and cotton gloves as sampling media, with protective clothing worn beneath the cotton media to protect the operator. The quantitative determination of captan was done by gas chromatography-electron capture detector (GC-ECD), with the analytical method validated by measuring limits of detection and quantification, linear ranges, sample recovery and precision. Special emphasis is placed on factors that affected the stability of captan during chromatographic determination. The data generated for potential dermal exposure are presented separately for mixing/loading and application activities. These data are compared with values obtained with visible tracers using a similar field technique. Margin of safety (MOS) values are also calculated for the agricultural procedures studied.Fil: Hughes, Enrique Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Zalts, Anita. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Ojeda, Javier J.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Flores, Andrea P.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaFil: Glass, Richard C.. Food and Rural Affairs; Estados UnidosFil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; ArgentinaJohn Wiley & Sons Ltd2006-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/79896Hughes, Enrique Alejandro; Zalts, Anita; Ojeda, Javier J.; Flores, Andrea P.; Glass, Richard C.; et al.; Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina; John Wiley & Sons Ltd; Pest Management Science; 62; 9; 9-2006; 811-8181526-498XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ps.1232info:eu-repo/semantics/altIdentifier/doi/10.1002/ps.1232info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:07:58Zoai:ri.conicet.gov.ar:11336/79896instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:07:58.485CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina |
title |
Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina |
spellingShingle |
Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina Hughes, Enrique Alejandro Captan Gc-Ecd Periurban Agriculture Potential Dermal Exposure |
title_short |
Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina |
title_full |
Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina |
title_fullStr |
Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina |
title_full_unstemmed |
Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina |
title_sort |
Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina |
dc.creator.none.fl_str_mv |
Hughes, Enrique Alejandro Zalts, Anita Ojeda, Javier J. Flores, Andrea P. Glass, Richard C. Montserrat, Javier Marcelo |
author |
Hughes, Enrique Alejandro |
author_facet |
Hughes, Enrique Alejandro Zalts, Anita Ojeda, Javier J. Flores, Andrea P. Glass, Richard C. Montserrat, Javier Marcelo |
author_role |
author |
author2 |
Zalts, Anita Ojeda, Javier J. Flores, Andrea P. Glass, Richard C. Montserrat, Javier Marcelo |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
Captan Gc-Ecd Periurban Agriculture Potential Dermal Exposure |
topic |
Captan Gc-Ecd Periurban Agriculture Potential Dermal Exposure |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
An analytical method has been developed that can be used to determine the potential dermal exposure (PDE) of workers to the pesticide captan in small-scale horticultural production units. The methodology is based on the whole body dosimetry technique, using a cotton coverall and cotton gloves as sampling media, with protective clothing worn beneath the cotton media to protect the operator. The quantitative determination of captan was done by gas chromatography-electron capture detector (GC-ECD), with the analytical method validated by measuring limits of detection and quantification, linear ranges, sample recovery and precision. Special emphasis is placed on factors that affected the stability of captan during chromatographic determination. The data generated for potential dermal exposure are presented separately for mixing/loading and application activities. These data are compared with values obtained with visible tracers using a similar field technique. Margin of safety (MOS) values are also calculated for the agricultural procedures studied. Fil: Hughes, Enrique Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina Fil: Zalts, Anita. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina Fil: Ojeda, Javier J.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina Fil: Flores, Andrea P.. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina Fil: Glass, Richard C.. Food and Rural Affairs; Estados Unidos Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de General Sarmiento. Instituto de Ciencias; Argentina |
description |
An analytical method has been developed that can be used to determine the potential dermal exposure (PDE) of workers to the pesticide captan in small-scale horticultural production units. The methodology is based on the whole body dosimetry technique, using a cotton coverall and cotton gloves as sampling media, with protective clothing worn beneath the cotton media to protect the operator. The quantitative determination of captan was done by gas chromatography-electron capture detector (GC-ECD), with the analytical method validated by measuring limits of detection and quantification, linear ranges, sample recovery and precision. Special emphasis is placed on factors that affected the stability of captan during chromatographic determination. The data generated for potential dermal exposure are presented separately for mixing/loading and application activities. These data are compared with values obtained with visible tracers using a similar field technique. Margin of safety (MOS) values are also calculated for the agricultural procedures studied. |
publishDate |
2006 |
dc.date.none.fl_str_mv |
2006-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/79896 Hughes, Enrique Alejandro; Zalts, Anita; Ojeda, Javier J.; Flores, Andrea P.; Glass, Richard C.; et al.; Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina; John Wiley & Sons Ltd; Pest Management Science; 62; 9; 9-2006; 811-818 1526-498X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/79896 |
identifier_str_mv |
Hughes, Enrique Alejandro; Zalts, Anita; Ojeda, Javier J.; Flores, Andrea P.; Glass, Richard C.; et al.; Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina; John Wiley & Sons Ltd; Pest Management Science; 62; 9; 9-2006; 811-818 1526-498X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/ps.1232 info:eu-repo/semantics/altIdentifier/doi/10.1002/ps.1232 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
John Wiley & Sons Ltd |
publisher.none.fl_str_mv |
John Wiley & Sons Ltd |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842270025618030592 |
score |
13.13397 |