Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate Environment

Autores
Rossetti, Agustín; Ikumi, Tai; Segura, Ignacio; Irassar, Edgardo Fabián
Año de publicación
2019
Idioma
inglés
Tipo de recurso
documento de conferencia
Estado
versión publicada
Descripción
The use of ternary blended cements with limestone filler and calcined clays can improve the durability of concrete structures exposed to aggressive environ-ments and extend their service life. In sulfate-rich environments, the effects of supple-mentary cementitious materials depend on the replacement level and the progress of hydration. Low level of limestone filler contributes to the stabilization of AFt due to formation of monocarboaluminate. However, high replacement increases the effective w/c ratio and the capillary porosity, favoring the sulfate penetration. The use of active pozzolans improves sulfate resistance by reducing portlandite content and the permea-bility, which minimize ettringite and gypsum formation and sulfate penetration. It is generally assumed that curing prior to sulfate exposure should be extended to allow the pozzolanic reaction to progress. It is currently uncertain the effectiveness of calcined clay in combination with limestone filler when the cement is exposed immediately to aggressive environments. Typical structures affected by sulfate attack are commonly build in situ, thus being exposed to the aggressive environment since casting. This paper analyses external sulfate attack of blended cements with 30 % replacement by combinations of limestone filler and/or calcined clay exposed to Na2SO4 solution at two days after casting. For that, expansions, mass variation, visual appearance and com-pressive strength are monitored in mortars and pastes during 6 months. The evolution of microstructure was evaluated with XRD. Despite the lack of curing prior to sulfate exposure, cement with calcined clay showed an excellent resistance to external sulfate attack, while limestone cements presented a worse performance.
Materia
Ingeniería de los Materiales
Illite calcined clay
Limestone filler
Sulfate attack
Curing
Early exposed
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/4.0/
Repositorio
CIC Digital (CICBA)
Institución
Comisión de Investigaciones Científicas de la Provincia de Buenos Aires
OAI Identificador
oai:digital.cic.gba.gob.ar:11746/10882

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repository_id_str 9441
network_name_str CIC Digital (CICBA)
spelling Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate EnvironmentRossetti, AgustínIkumi, TaiSegura, IgnacioIrassar, Edgardo FabiánIngeniería de los MaterialesIllite calcined clayLimestone fillerSulfate attackCuringEarly exposedThe use of ternary blended cements with limestone filler and calcined clays can improve the durability of concrete structures exposed to aggressive environ-ments and extend their service life. In sulfate-rich environments, the effects of supple-mentary cementitious materials depend on the replacement level and the progress of hydration. Low level of limestone filler contributes to the stabilization of AFt due to formation of monocarboaluminate. However, high replacement increases the effective w/c ratio and the capillary porosity, favoring the sulfate penetration. The use of active pozzolans improves sulfate resistance by reducing portlandite content and the permea-bility, which minimize ettringite and gypsum formation and sulfate penetration. It is generally assumed that curing prior to sulfate exposure should be extended to allow the pozzolanic reaction to progress. It is currently uncertain the effectiveness of calcined clay in combination with limestone filler when the cement is exposed immediately to aggressive environments. Typical structures affected by sulfate attack are commonly build in situ, thus being exposed to the aggressive environment since casting. This paper analyses external sulfate attack of blended cements with 30 % replacement by combinations of limestone filler and/or calcined clay exposed to Na2SO4 solution at two days after casting. For that, expansions, mass variation, visual appearance and com-pressive strength are monitored in mortars and pastes during 6 months. The evolution of microstructure was evaluated with XRD. Despite the lack of curing prior to sulfate exposure, cement with calcined clay showed an excellent resistance to external sulfate attack, while limestone cements presented a worse performance.2019-10info:eu-repo/semantics/conferenceObjectinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_5794info:ar-repo/semantics/documentoDeConferenciaapplication/pdfhttps://digital.cic.gba.gob.ar/handle/11746/10882enginfo:eu-repo/semantics/altIdentifier/doi/10.1007/978-981-15-2806-4_73info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/reponame:CIC Digital (CICBA)instname:Comisión de Investigaciones Científicas de la Provincia de Buenos Airesinstacron:CICBA2025-09-29T13:40:21Zoai:digital.cic.gba.gob.ar:11746/10882Institucionalhttp://digital.cic.gba.gob.arOrganismo científico-tecnológicoNo correspondehttp://digital.cic.gba.gob.ar/oai/snrdmarisa.degiusti@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:94412025-09-29 13:40:21.348CIC Digital (CICBA) - Comisión de Investigaciones Científicas de la Provincia de Buenos Airesfalse
dc.title.none.fl_str_mv Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate Environment
title Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate Environment
spellingShingle Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate Environment
Rossetti, Agustín
Ingeniería de los Materiales
Illite calcined clay
Limestone filler
Sulfate attack
Curing
Early exposed
title_short Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate Environment
title_full Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate Environment
title_fullStr Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate Environment
title_full_unstemmed Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate Environment
title_sort Performance of Blended Cements with Limestone Filler and Illitic Calcined Clay Immediately Exposed to Sulfate Environment
dc.creator.none.fl_str_mv Rossetti, Agustín
Ikumi, Tai
Segura, Ignacio
Irassar, Edgardo Fabián
author Rossetti, Agustín
author_facet Rossetti, Agustín
Ikumi, Tai
Segura, Ignacio
Irassar, Edgardo Fabián
author_role author
author2 Ikumi, Tai
Segura, Ignacio
Irassar, Edgardo Fabián
author2_role author
author
author
dc.subject.none.fl_str_mv Ingeniería de los Materiales
Illite calcined clay
Limestone filler
Sulfate attack
Curing
Early exposed
topic Ingeniería de los Materiales
Illite calcined clay
Limestone filler
Sulfate attack
Curing
Early exposed
dc.description.none.fl_txt_mv The use of ternary blended cements with limestone filler and calcined clays can improve the durability of concrete structures exposed to aggressive environ-ments and extend their service life. In sulfate-rich environments, the effects of supple-mentary cementitious materials depend on the replacement level and the progress of hydration. Low level of limestone filler contributes to the stabilization of AFt due to formation of monocarboaluminate. However, high replacement increases the effective w/c ratio and the capillary porosity, favoring the sulfate penetration. The use of active pozzolans improves sulfate resistance by reducing portlandite content and the permea-bility, which minimize ettringite and gypsum formation and sulfate penetration. It is generally assumed that curing prior to sulfate exposure should be extended to allow the pozzolanic reaction to progress. It is currently uncertain the effectiveness of calcined clay in combination with limestone filler when the cement is exposed immediately to aggressive environments. Typical structures affected by sulfate attack are commonly build in situ, thus being exposed to the aggressive environment since casting. This paper analyses external sulfate attack of blended cements with 30 % replacement by combinations of limestone filler and/or calcined clay exposed to Na2SO4 solution at two days after casting. For that, expansions, mass variation, visual appearance and com-pressive strength are monitored in mortars and pastes during 6 months. The evolution of microstructure was evaluated with XRD. Despite the lack of curing prior to sulfate exposure, cement with calcined clay showed an excellent resistance to external sulfate attack, while limestone cements presented a worse performance.
description The use of ternary blended cements with limestone filler and calcined clays can improve the durability of concrete structures exposed to aggressive environ-ments and extend their service life. In sulfate-rich environments, the effects of supple-mentary cementitious materials depend on the replacement level and the progress of hydration. Low level of limestone filler contributes to the stabilization of AFt due to formation of monocarboaluminate. However, high replacement increases the effective w/c ratio and the capillary porosity, favoring the sulfate penetration. The use of active pozzolans improves sulfate resistance by reducing portlandite content and the permea-bility, which minimize ettringite and gypsum formation and sulfate penetration. It is generally assumed that curing prior to sulfate exposure should be extended to allow the pozzolanic reaction to progress. It is currently uncertain the effectiveness of calcined clay in combination with limestone filler when the cement is exposed immediately to aggressive environments. Typical structures affected by sulfate attack are commonly build in situ, thus being exposed to the aggressive environment since casting. This paper analyses external sulfate attack of blended cements with 30 % replacement by combinations of limestone filler and/or calcined clay exposed to Na2SO4 solution at two days after casting. For that, expansions, mass variation, visual appearance and com-pressive strength are monitored in mortars and pastes during 6 months. The evolution of microstructure was evaluated with XRD. Despite the lack of curing prior to sulfate exposure, cement with calcined clay showed an excellent resistance to external sulfate attack, while limestone cements presented a worse performance.
publishDate 2019
dc.date.none.fl_str_mv 2019-10
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dc.identifier.none.fl_str_mv https://digital.cic.gba.gob.ar/handle/11746/10882
url https://digital.cic.gba.gob.ar/handle/11746/10882
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/978-981-15-2806-4_73
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http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
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dc.source.none.fl_str_mv reponame:CIC Digital (CICBA)
instname:Comisión de Investigaciones Científicas de la Provincia de Buenos Aires
instacron:CICBA
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repository.name.fl_str_mv CIC Digital (CICBA) - Comisión de Investigaciones Científicas de la Provincia de Buenos Aires
repository.mail.fl_str_mv marisa.degiusti@sedici.unlp.edu.ar
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