N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds

Autores
Suarez, S.A.; Foi, A.; Eady, S.; Larsen, A.; Doctorovich, F.
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.
Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fuente
Acta Crystallogr Sect C Cryst Struct Commun 2011;67(10):o417-o420
Materia
Asymmetric unit
Carborane anions
Carborane cages
Counterions
Pyridinium salts
Title compounds
Positive ions
Negative ions
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/2.5/ar
Repositorio
Biblioteca Digital (UBA-FCEN)
Institución
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
OAI Identificador
paperaa:paper_01082701_v67_n10_po417_Suarez
Acceder
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oai_identifier_str paperaa:paper_01082701_v67_n10_po417_Suarez
network_acronym_str BDUBAFCEN
repository_id_str 1896
network_name_str Biblioteca Digital (UBA-FCEN)
spelling N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compoundsSuarez, S.A.Foi, A.Eady, S.Larsen, A.Doctorovich, F.Asymmetric unitCarborane anionsCarborane cagesCounterionsPyridinium saltsTitle compoundsPositive ionsNegative ionsThe title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.2011info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_SuarezActa Crystallogr Sect C Cryst Struct Commun 2011;67(10):o417-o420reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2025-10-23T11:18:24Zpaperaa:paper_01082701_v67_n10_po417_SuarezInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962025-10-23 11:18:26.529Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse
dc.title.none.fl_str_mv N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
spellingShingle N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
Suarez, S.A.
Asymmetric unit
Carborane anions
Carborane cages
Counterions
Pyridinium salts
Title compounds
Positive ions
Negative ions
title_short N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_full N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_fullStr N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_full_unstemmed N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_sort N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
dc.creator.none.fl_str_mv Suarez, S.A.
Foi, A.
Eady, S.
Larsen, A.
Doctorovich, F.
author Suarez, S.A.
author_facet Suarez, S.A.
Foi, A.
Eady, S.
Larsen, A.
Doctorovich, F.
author_role author
author2 Foi, A.
Eady, S.
Larsen, A.
Doctorovich, F.
author2_role author
author
author
author
dc.subject.none.fl_str_mv Asymmetric unit
Carborane anions
Carborane cages
Counterions
Pyridinium salts
Title compounds
Positive ions
Negative ions
topic Asymmetric unit
Carborane anions
Carborane cages
Counterions
Pyridinium salts
Title compounds
Positive ions
Negative ions
dc.description.none.fl_txt_mv The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.
Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
description The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.
publishDate 2011
dc.date.none.fl_str_mv 2011
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez
url http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/ar
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv Acta Crystallogr Sect C Cryst Struct Commun 2011;67(10):o417-o420
reponame:Biblioteca Digital (UBA-FCEN)
instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron:UBA-FCEN
reponame_str Biblioteca Digital (UBA-FCEN)
collection Biblioteca Digital (UBA-FCEN)
instname_str Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron_str UBA-FCEN
institution UBA-FCEN
repository.name.fl_str_mv Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
repository.mail.fl_str_mv ana@bl.fcen.uba.ar
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score 12.982451

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