Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties

Autores
Zaccari, D.G.; De Azúa, M.C.R.; Melo, J.I.; Giribet, C.G.
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In the present work a set of formal relations connecting different approaches to calculate relativistic effects on magnetic molecular properties are proven. The linear response (LR) within the elimination of the small component (ESC), Breit Pauli, and minimal-coupling approaches are compared. To this end, the leading order ESC reduction of operators within the minimal-coupling four-component approach is carried out. The equivalence of all three approaches within the ESC approximation is proven. It is numerically verified for the NMR nuclear-magnetic shielding tensor taking HX and C H3 X (X=Br,I) as model compounds. Formal relations proving the gauge origin invariance of the full relativistic effect on the NMR nuclear-magnetic shielding tensor within the LR-ESC approach are presented. © 2006 American Institute of Physics.
Fil:Zaccari, D.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Melo, J.I. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Giribet, C.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fuente
J Chem Phys 2006;124(5)
Materia
Elimination of the small component (ESC)
Linear response (LR)
Molecular magnetic properties
Relativistic effect
Magnetic properties
Magnetic shielding
Mathematical operators
Nuclear magnetic resonance
Tensors
Molecular dynamics
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by/2.5/ar
Repositorio
Biblioteca Digital (UBA-FCEN)
Institución
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
OAI Identificador
paperaa:paper_00219606_v124_n5_p_Zaccari

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oai_identifier_str paperaa:paper_00219606_v124_n5_p_Zaccari
network_acronym_str BDUBAFCEN
repository_id_str 1896
network_name_str Biblioteca Digital (UBA-FCEN)
spelling Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic propertiesZaccari, D.G.De Azúa, M.C.R.Melo, J.I.Giribet, C.G.Elimination of the small component (ESC)Linear response (LR)Molecular magnetic propertiesRelativistic effectMagnetic propertiesMagnetic shieldingMathematical operatorsNuclear magnetic resonanceTensorsMolecular dynamicsIn the present work a set of formal relations connecting different approaches to calculate relativistic effects on magnetic molecular properties are proven. The linear response (LR) within the elimination of the small component (ESC), Breit Pauli, and minimal-coupling approaches are compared. To this end, the leading order ESC reduction of operators within the minimal-coupling four-component approach is carried out. The equivalence of all three approaches within the ESC approximation is proven. It is numerically verified for the NMR nuclear-magnetic shielding tensor taking HX and C H3 X (X=Br,I) as model compounds. Formal relations proving the gauge origin invariance of the full relativistic effect on the NMR nuclear-magnetic shielding tensor within the LR-ESC approach are presented. © 2006 American Institute of Physics.Fil:Zaccari, D.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Melo, J.I. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Giribet, C.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.2006info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_00219606_v124_n5_p_ZaccariJ Chem Phys 2006;124(5)reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2025-09-29T13:43:09Zpaperaa:paper_00219606_v124_n5_p_ZaccariInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962025-09-29 13:43:10.614Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse
dc.title.none.fl_str_mv Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties
title Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties
spellingShingle Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties
Zaccari, D.G.
Elimination of the small component (ESC)
Linear response (LR)
Molecular magnetic properties
Relativistic effect
Magnetic properties
Magnetic shielding
Mathematical operators
Nuclear magnetic resonance
Tensors
Molecular dynamics
title_short Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties
title_full Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties
title_fullStr Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties
title_full_unstemmed Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties
title_sort Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties
dc.creator.none.fl_str_mv Zaccari, D.G.
De Azúa, M.C.R.
Melo, J.I.
Giribet, C.G.
author Zaccari, D.G.
author_facet Zaccari, D.G.
De Azúa, M.C.R.
Melo, J.I.
Giribet, C.G.
author_role author
author2 De Azúa, M.C.R.
Melo, J.I.
Giribet, C.G.
author2_role author
author
author
dc.subject.none.fl_str_mv Elimination of the small component (ESC)
Linear response (LR)
Molecular magnetic properties
Relativistic effect
Magnetic properties
Magnetic shielding
Mathematical operators
Nuclear magnetic resonance
Tensors
Molecular dynamics
topic Elimination of the small component (ESC)
Linear response (LR)
Molecular magnetic properties
Relativistic effect
Magnetic properties
Magnetic shielding
Mathematical operators
Nuclear magnetic resonance
Tensors
Molecular dynamics
dc.description.none.fl_txt_mv In the present work a set of formal relations connecting different approaches to calculate relativistic effects on magnetic molecular properties are proven. The linear response (LR) within the elimination of the small component (ESC), Breit Pauli, and minimal-coupling approaches are compared. To this end, the leading order ESC reduction of operators within the minimal-coupling four-component approach is carried out. The equivalence of all three approaches within the ESC approximation is proven. It is numerically verified for the NMR nuclear-magnetic shielding tensor taking HX and C H3 X (X=Br,I) as model compounds. Formal relations proving the gauge origin invariance of the full relativistic effect on the NMR nuclear-magnetic shielding tensor within the LR-ESC approach are presented. © 2006 American Institute of Physics.
Fil:Zaccari, D.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Melo, J.I. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Giribet, C.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
description In the present work a set of formal relations connecting different approaches to calculate relativistic effects on magnetic molecular properties are proven. The linear response (LR) within the elimination of the small component (ESC), Breit Pauli, and minimal-coupling approaches are compared. To this end, the leading order ESC reduction of operators within the minimal-coupling four-component approach is carried out. The equivalence of all three approaches within the ESC approximation is proven. It is numerically verified for the NMR nuclear-magnetic shielding tensor taking HX and C H3 X (X=Br,I) as model compounds. Formal relations proving the gauge origin invariance of the full relativistic effect on the NMR nuclear-magnetic shielding tensor within the LR-ESC approach are presented. © 2006 American Institute of Physics.
publishDate 2006
dc.date.none.fl_str_mv 2006
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12110/paper_00219606_v124_n5_p_Zaccari
url http://hdl.handle.net/20.500.12110/paper_00219606_v124_n5_p_Zaccari
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/2.5/ar
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/ar
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv J Chem Phys 2006;124(5)
reponame:Biblioteca Digital (UBA-FCEN)
instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron:UBA-FCEN
reponame_str Biblioteca Digital (UBA-FCEN)
collection Biblioteca Digital (UBA-FCEN)
instname_str Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron_str UBA-FCEN
institution UBA-FCEN
repository.name.fl_str_mv Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
repository.mail.fl_str_mv ana@bl.fcen.uba.ar
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score 13.070432