Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties
- Autores
- Zaccari, D.G.; De Azúa, M.C.R.; Melo, J.I.; Giribet, C.G.
- Año de publicación
- 2006
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In the present work a set of formal relations connecting different approaches to calculate relativistic effects on magnetic molecular properties are proven. The linear response (LR) within the elimination of the small component (ESC), Breit Pauli, and minimal-coupling approaches are compared. To this end, the leading order ESC reduction of operators within the minimal-coupling four-component approach is carried out. The equivalence of all three approaches within the ESC approximation is proven. It is numerically verified for the NMR nuclear-magnetic shielding tensor taking HX and C H3 X (X=Br,I) as model compounds. Formal relations proving the gauge origin invariance of the full relativistic effect on the NMR nuclear-magnetic shielding tensor within the LR-ESC approach are presented. © 2006 American Institute of Physics.
Fil:Zaccari, D.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Melo, J.I. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Giribet, C.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. - Fuente
- J Chem Phys 2006;124(5)
- Materia
-
Elimination of the small component (ESC)
Linear response (LR)
Molecular magnetic properties
Relativistic effect
Magnetic properties
Magnetic shielding
Mathematical operators
Nuclear magnetic resonance
Tensors
Molecular dynamics - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- http://creativecommons.org/licenses/by/2.5/ar
- Repositorio
- Institución
- Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
- OAI Identificador
- paperaa:paper_00219606_v124_n5_p_Zaccari
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Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic propertiesZaccari, D.G.De Azúa, M.C.R.Melo, J.I.Giribet, C.G.Elimination of the small component (ESC)Linear response (LR)Molecular magnetic propertiesRelativistic effectMagnetic propertiesMagnetic shieldingMathematical operatorsNuclear magnetic resonanceTensorsMolecular dynamicsIn the present work a set of formal relations connecting different approaches to calculate relativistic effects on magnetic molecular properties are proven. The linear response (LR) within the elimination of the small component (ESC), Breit Pauli, and minimal-coupling approaches are compared. To this end, the leading order ESC reduction of operators within the minimal-coupling four-component approach is carried out. The equivalence of all three approaches within the ESC approximation is proven. It is numerically verified for the NMR nuclear-magnetic shielding tensor taking HX and C H3 X (X=Br,I) as model compounds. Formal relations proving the gauge origin invariance of the full relativistic effect on the NMR nuclear-magnetic shielding tensor within the LR-ESC approach are presented. © 2006 American Institute of Physics.Fil:Zaccari, D.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Melo, J.I. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.Fil:Giribet, C.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.2006info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://hdl.handle.net/20.500.12110/paper_00219606_v124_n5_p_ZaccariJ Chem Phys 2006;124(5)reponame:Biblioteca Digital (UBA-FCEN)instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesinstacron:UBA-FCENenginfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/ar2025-09-29T13:43:09Zpaperaa:paper_00219606_v124_n5_p_ZaccariInstitucionalhttps://digital.bl.fcen.uba.ar/Universidad públicaNo correspondehttps://digital.bl.fcen.uba.ar/cgi-bin/oaiserver.cgiana@bl.fcen.uba.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:18962025-09-29 13:43:10.614Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturalesfalse |
dc.title.none.fl_str_mv |
Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties |
title |
Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties |
spellingShingle |
Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties Zaccari, D.G. Elimination of the small component (ESC) Linear response (LR) Molecular magnetic properties Relativistic effect Magnetic properties Magnetic shielding Mathematical operators Nuclear magnetic resonance Tensors Molecular dynamics |
title_short |
Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties |
title_full |
Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties |
title_fullStr |
Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties |
title_full_unstemmed |
Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties |
title_sort |
Formal relations connecting different approaches to calculate relativistic effects on molecular magnetic properties |
dc.creator.none.fl_str_mv |
Zaccari, D.G. De Azúa, M.C.R. Melo, J.I. Giribet, C.G. |
author |
Zaccari, D.G. |
author_facet |
Zaccari, D.G. De Azúa, M.C.R. Melo, J.I. Giribet, C.G. |
author_role |
author |
author2 |
De Azúa, M.C.R. Melo, J.I. Giribet, C.G. |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Elimination of the small component (ESC) Linear response (LR) Molecular magnetic properties Relativistic effect Magnetic properties Magnetic shielding Mathematical operators Nuclear magnetic resonance Tensors Molecular dynamics |
topic |
Elimination of the small component (ESC) Linear response (LR) Molecular magnetic properties Relativistic effect Magnetic properties Magnetic shielding Mathematical operators Nuclear magnetic resonance Tensors Molecular dynamics |
dc.description.none.fl_txt_mv |
In the present work a set of formal relations connecting different approaches to calculate relativistic effects on magnetic molecular properties are proven. The linear response (LR) within the elimination of the small component (ESC), Breit Pauli, and minimal-coupling approaches are compared. To this end, the leading order ESC reduction of operators within the minimal-coupling four-component approach is carried out. The equivalence of all three approaches within the ESC approximation is proven. It is numerically verified for the NMR nuclear-magnetic shielding tensor taking HX and C H3 X (X=Br,I) as model compounds. Formal relations proving the gauge origin invariance of the full relativistic effect on the NMR nuclear-magnetic shielding tensor within the LR-ESC approach are presented. © 2006 American Institute of Physics. Fil:Zaccari, D.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Melo, J.I. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Giribet, C.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. |
description |
In the present work a set of formal relations connecting different approaches to calculate relativistic effects on magnetic molecular properties are proven. The linear response (LR) within the elimination of the small component (ESC), Breit Pauli, and minimal-coupling approaches are compared. To this end, the leading order ESC reduction of operators within the minimal-coupling four-component approach is carried out. The equivalence of all three approaches within the ESC approximation is proven. It is numerically verified for the NMR nuclear-magnetic shielding tensor taking HX and C H3 X (X=Br,I) as model compounds. Formal relations proving the gauge origin invariance of the full relativistic effect on the NMR nuclear-magnetic shielding tensor within the LR-ESC approach are presented. © 2006 American Institute of Physics. |
publishDate |
2006 |
dc.date.none.fl_str_mv |
2006 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/20.500.12110/paper_00219606_v124_n5_p_Zaccari |
url |
http://hdl.handle.net/20.500.12110/paper_00219606_v124_n5_p_Zaccari |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/2.5/ar |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
J Chem Phys 2006;124(5) reponame:Biblioteca Digital (UBA-FCEN) instname:Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales instacron:UBA-FCEN |
reponame_str |
Biblioteca Digital (UBA-FCEN) |
collection |
Biblioteca Digital (UBA-FCEN) |
instname_str |
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales |
instacron_str |
UBA-FCEN |
institution |
UBA-FCEN |
repository.name.fl_str_mv |
Biblioteca Digital (UBA-FCEN) - Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales |
repository.mail.fl_str_mv |
ana@bl.fcen.uba.ar |
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