Solvation dynamics following electron photodetachment from l- in aqueous clusters

Autores
<div class="autor_fcen" id="2789">Elola, M.D.</div>; <div class="autor_fcen" id="4817">Laria, D.</div>
Año de publicación
2002
Idioma
inglés
Tipo de recurso
artículo
Estado
Versión publicada
Descripción
New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the microscopic mechanisms that drive the reaction. These fluctuations, in turn, determine the characteristics of the electron localization and the subsequent detachment following photoexcitation of the probe.
Fil:Elola, M.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fil:Laria, D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina.
Fuente
J Chem Phys 2002;117(5):2238-2245
Materia
Algorithms
Chemical relaxation
Diffusion
Electronic properties
Ground state
Mathematical models
Molecular structure
Photochemical reactions
Quantum theory
Solutions
Diffuse density profile
Electron photodetachment
Electronic excitation
Equilibrium solvation structures
Solvation dynamics
Surface states
Molecular dynamics
Nivel de accesibilidad
Acceso abierto
Licencia
http://creativecommons.org/licenses/by/2.5/ar
Repositorio
Biblioteca Digital (UBA-FCEN)
Institución
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
OAI Identificador
snrd:HASH22f27bbac42a6749f867ea